A kind of anti-slip coating for sports equipment
An anti-slip coating and sports technology, applied in the field of coatings, can solve the problems of short application life, easy injury of sports equipment, and large proportion of anti-slip agent
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Embodiment 1
[0037] Synthesis of Modified Amino Silicone Resin
[0038] The synthetic route of described modified aminosilicone resin is:
[0039]
[0040] The specific synthesis method is:
[0041] (1) Add 10mol of amino silicone resin 1, 22mol of modifier maleic anhydride 2 and 100ml of solvent N,N-dimethylformamide into the reaction flask, and heat to 90°C under nitrogen atmosphere for acylation reaction After 60 minutes, 0.3mol phosphotungstic acid was added, the temperature was raised to 145°C, and the ring closure and dehydration reaction was carried out for 3 hours, and the amide intermediate 3 was obtained;
[0042] (2) After the reaction in step (1), the temperature was lowered to 15° C., 40 mol of peracetic acid was added, and the epoxidation reaction was carried out with slow stirring for 1.5 hours to obtain a modified amino silicone resin 4 containing epoxy groups and amide groups. The rate is 97.8;
[0043] The proton nuclear magnetic spectrum result of gained target pro...
Embodiment 2
[0045] Preparation of composite anti-slip agent
[0046] The parts by mass of the raw materials of the composite anti-slip agent are: 5 parts of silk fiber, 16 parts of montmorillonite powder, and 1 part of 0.8% ethanol solution of acetoxyethoxysilane;
[0047] The preparation method of the composite anti-slip agent is as follows: uniformly mix silk fiber and montmorillonite powder, and dry at 105°C for 24 hours. After drying, add ethanol to disperse into a suspension, add dropwise acetic acid to adjust the pH value to 4.2, add 0.8% ethanol solution of acetoxyethoxysilane was ultrasonically dispersed at 20kHz for 3min, transferred to a reaction bottle and heated at 65°C, stirred for 1h, vacuum filtered, washed with ethanol, and dried under reduced pressure at 45°C for 5h to obtain Composite anti-slip agent.
Embodiment 3
[0049] An anti-slip coating for sports equipment, the weight percentage of each raw material is: 30% of modified amino silicone resin, 12% of titanium dioxide, 12% of cerium oxide, 10% of composite anti-slip agent, 2% of coupling agent, curing agent 5%, leveling agent 0.5%, defoamer 0.5%, acetone 28%;
[0050] The particle size of the titanium dioxide is 1-35nm; the particle size of the cerium oxide is 7-45nm;
[0051] Described coupling agent is the composite of silane coupling agent and tin tetrachloride, and the weight ratio of silane coupling agent and tin tetrachloride is 1:0.1;
[0052] The preparation method of this antiskid coating specifically comprises the following steps:
[0053] S1. Dissolve the modified amino silicone resin with solvent acetone, add coupling agent, curing agent, leveling agent, defoamer while stirring, mix well, and set aside;
[0054] S2. Put titanium dioxide, cerium oxide and composite anti-slip agent into a ball mill for grinding and mixing,...
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