Efficient wetting purifying agent and application thereof to environment purification

A purifying agent and high-efficiency technology, applied in the field of environmental purification, can solve the problems of poor stability of adsorbent adsorption effect, inability to suspend, and single density, and achieve the effect of strong purification endurance, easy immobilization operation, and large bacterial load.

Active Publication Date: 2019-06-25
华沃德源环境技术(济南)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, in the cell immobilization technology, the embedding method is to disperse the cells into the porous carrier, or use the polymer to embed the cells inside when the gel is formed, so as to achieve the purpose of fixing the cells, which is currently the most widely used. However, when using the biological metabolic function of sulfur-oxidizing bacteria to treat sulfur-containing wastewater, the metabolic activities of functional microorganisms in the reactor are often inhibited due to the high concentration of sulfide in the influent, resulting in the need for a long time for functional microorganisms. Long adaptation period, and because the adhesion of sulfur oxidizing bacteria is not strong, it is easy to lose with the effluent, so it is not easy to maintain a high concentration of sulfur oxidizing bacteria in the reactor
[0004] Such as CN103951052 A Beijing University of Technology discloses the preparation and application of a polyurethane carrier-based sulfur-oxidizing bacteria immobilized bioactive filler, blocky polyurethane foam is solidified by extruding and absorbing the embedding fluid to absorb and solidify the embedding fluid loaded with sulfur-oxidizing bacteria However, the polyurethane material has the following problems: (1) The density is single, and there are only two states of floating and sinking. In the dynamic system of water body changes, it cannot be effectively used for a long time. Suspended in water; (2) Polyurethane has no sites on the surface and is not suitable for establishing sites, so it is not suitable for selective adsorption of sulfur oxidizing bacteria; (3) Polyurethane has a single pore size and only has irregular macropores , although the large pores are good for adsorption, the specific surface area is extremely small, the fixation effect is poor, and the stability is somewhat improved; (3) Polyurethane, as an organic high polymer, will cause serious pollution. A cube with a length of 3‐5mm, a cuboid with a length, width and height of 3‐5mm, a cylinder with a diameter of 3‐5mm and a height of 3‐5mm, etc., are similar to the carrier of particles. After purifying large areas of water such as lakes and oceans, There are huge problems in recycling, which can easily cause pollution
However, the polyurethane material has the following problems: (1) the carrier is complex, and it is difficult to mix evenly, which makes it impossible to achieve homogeneous mixing, resulting in poor stability of the adsorption effect of the entire adsorbent; (2) no effective adsorption vacancies, only relying on the Sequential macroporous adsorption of bacteria, single adsorption
[0006] In addition, in the inventor’s series of applications on the same day, the method of attaching sulfur-oxidizing bacteria by calibration and the water purification agent obtained by this method have the following problems that need to be improved: (1) The purification effect of the purification agent on water bodies Excellent and high efficiency, but when used for domestic sludge, such as Wuxi Meiliang Lake coastal sludge purification, due to the low water content of the sludge, the purification effect of the purifier cannot be fully exerted; (2) Although the calibration can effectively attach sulfur (3) The loading capacity of sulfur oxidizing bacteria needs to be improved; (4) Purifiers can purify water continuously for 1-1.5 years under stable laboratory conditions, but In the complex actual use process, the ability of continuous purification is poor; (5) The mechanical strength of the silica carrier becomes a fatal flaw in the application process due to the existence of macropores and mesopores

Method used

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  • Efficient wetting purifying agent and application thereof to environment purification
  • Efficient wetting purifying agent and application thereof to environment purification

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A preparation method of a wetting water purifying agent comprises the steps:

[0040] (1) Preparation of carrier particles: the carrier is a macroporous mesoporous silica carrier with interconnected and penetrating pore structures, and connected pore windows of 1-10 μm are attached to the pore walls, and the pore walls are composed of mesoporous morphology structures.

[0041] (2) Reduction-sulfurization of the carrier: place the carrier in a corundum cup in a vacuum tube furnace, ventilate it with argon gas, and then switch the gas path to 3vol.H 2 / Ar mixture, warm up to 570 o C, the time is 1.25h, naturally cool down to 250 o After C, after argon is evacuated, CS is introduced 2 gas to 13 o C / min increased to 700 o C, keep the temperature for 1.5h, cool down to room temperature naturally, form sulfur-oxygen bonds on the surface of the silica carrier, and serve as the adsorption sites for the culture medium sulfur bacteria.

[0042] (3) Prepare sulfur-oxidizing b...

Embodiment 2-3

[0049] The preparation method is consistent with Example 1, except that sodium alginate (SA), polyethylene glycol (PVA), calcium chloride (CaCl 2 ) are used in different amounts, see Table 1 for details, named S-2 and S-3.

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Abstract

The invention provides an efficient wetting purifying agent. The wetting purifying agent is 12 to 23 percent in water content. According to the purifying agent provided by the invention, the wetting capability of the purifying agent is effectively improved through reduction-vulcanization and crosslinking reaction; the purifying agent has higher purifying capacity for pollutants with less moisturesuch as sludge and farmland soil, and has high purification cruising ability; the mechanical strength of a purifying agent carrier is relatively high.

Description

[0001] The invention belongs to the field of environmental purification, and in particular relates to a high-efficiency wetting and purifying agent and its application in the field of environmental purification. Background technique [0002] Studies have shown that in today's aquaculture process, due to the low bait utilization rate, excessive discharge of residual bait, and excessive discharge of farmed animal feces, eutrophication of water bodies, C, N, and P enrichment pollution of sediments and sediment oxidation are caused. The reduction potential is lowered. Increased eutrophication of water bodies will lead to excessive ammonia nitrogen and nitrite, which will have a toxic effect on aquatic animals. The discharge of a large amount of aquaculture wastewater has caused a huge impact on the surrounding environment. The water environment has deteriorated, red tides have occurred frequently, and ecological balance and biodiversity have also been destroyed. The decline in wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F3/34B09C1/10C02F103/20
Inventor 白洋洋
Owner 华沃德源环境技术(济南)有限公司
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