High temperature resistant paint for glass fibre reinforced plastic grille

A high-temperature-resistant coating and FRP technology, which is applied in the direction of fire-resistant coatings, polyester coatings, epoxy resin coatings, etc., can solve the problems of affecting the normal use of materials, poor adhesion of FRP grids, and the inability to reach the blocking temperature, etc., to achieve reduction Effects of smoke release, improved weather resistance, and extended protection period

Active Publication Date: 2004-12-08
CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This coating usually uses two types of base materials: solvent-based base materials based on acrylic acid, branched polyester and other resins, and water-based base materials based on sodium silicate. The solvent-based base material itself is not resistant to high temperatures. This type of coating mainly obtains high temperature resistance by adding a large amount of ceramic fillers, but a large amount of additives will inevitably reduce the internal strength of the coating, thereby affecting the normal use of the material; although the water-based base material based on sodium silicate can withstand high temperature , but the adhesion to the FRP grating with phenolic resin, unsaturated polyester resin, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Example 1 Preparation of Organic Resin Modified by Silicone Resin

[0037] 1. See Table 1 for the formula

[0038]

raw material name

Specification

Dosage

Resin 1

Resin 2

Resin 3

Resin 4

Silicone resin 1

Aryl / alkyl ratio 0.8

45

40

-

25

Silicone resin 2

Aryl / alkyl ratio 0.3

-

-

20

-

Organic Resin Epoxy Resin

Acrylic

polyester resin

polyimide resin

601#

55

-

-

-

-

60

-

-

-

-

80

-

-

-

-

75

Hydroxyl value, mgKOH / g

79

48

75

37

Silicone resin accounts for the total amount of resin

percentage, %

45

40

2

25

[0039] In Table 1: in silicone resin 1, aryl is phenyl, 20% of alkyl is ethyl, and 80% is m...

Embodiment 2

[0046] Example 2 Preparation of high temperature resistant coating 1 for FRP grid of the present invention

[0047] 1. See Table 2 for the formula

[0048] components

Raw material name and specification

Dosage

A

Group

Minute

①Silicone-modified organic resin

Embodiment 1 self-made resin 1, solid content 65%

40

② Pigment

Mica Iron Oxide

10

filler

Aluminum hydroxide

2

Mica powder

6

Talc powder

7

ceramic powder

4

[0049] glass powder

6

③Auxiliary Flame retardant-smoke suppressant

Ammonium polyphosphate

2.5

coupling agent

Tris(dioctylphosphoryloxy)isopropyl titanate

2.0

curing accelerator

Dibutyltin dilaurate

0.5

④Solvent

Xylene / Ethylene Glycol Ether Acetate / Butanone

(7:2:1)

20

B

Group

Minute

NCO-based polyurethane curing agent

...

Embodiment 3

[0053] Example 3 Preparation of high temperature resistant coating 2 for FRP grid of the present invention

[0054] 1. See Table 3 for the formula

[0055] components

Raw material name and specification

Dosage

A

Group

Minute

①Silicone-modified organic resin

Self-made resin 2 of embodiment 1, solid bowl content 65%

25

Real spin example 1 self-made resin 3, solid content 65%

20

② Pigment

Titanium dioxide

4

filler

composite metal oxide

10

Mica powder

6

ceramic powder

4

glass powder

6

③Auxiliary Flame retardant-smoke suppressant

Alkyl ferrocene

1.3

Zinc borate, extra fine

2.2

[0056] coupling agent

Complex phosphoric acid monoalkyl titanate

1.7

γ-Glycidyl etheroxypropyl trimethoxysilane

1.0

curing accelerator

Dibutyltin dilaurate

0.8

UV Scree...

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PUM

PropertyMeasurementUnit
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Abstract

A refractory paint for the grate made of glass fibre reinforced plastics contains component A and component B, which are proportionally mixed before used. Said component A is prepared from organosilicon resin modified organic resin, high-temp stable pigment and filler, flame retarding-smoke inhibiting agent, coupling agent, solidifying promoter, and UV absorbing or shielding assistant. Said component B is polyurethane solidifying agent containing NCO. Its advantages are high resistance to high temp (900 deg.C) and weatherability and low smoke density at high temp.

Description

technical field [0001] The invention relates to a high-temperature-resistant coating for FRP grids. Background technique [0002] FRP grating is a kind of glass fiber reinforced plastic products. Because of its advantages of light weight, high strength, chemical corrosion resistance, electrical insulation, heat insulation, excellent designability and constructability, it has been rapidly expanded from the initial application in military industry to construction, shipbuilding, automobile, petrochemical and other fields. field. However, since FRP grating is made of synthetic resin (such as epoxy, phenolic, unsaturated polyester resin, etc.) It is also flammable and emits toxic gas and a lot of smoke when burned. According to statistics, about 80% of the fatal accidents in fires are caused by suffocation of toxic gases and smoke produced during the thermal decomposition of materials in the early stage of fire. The best way to solve this problem is to apply a layer of paint ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/18C09D133/02C09D163/00C09D167/06C09D183/00
Inventor 狄志刚袁立新傅敏朱晓丰
Owner CNOOC CHANGZHOU PAINT & COATINGS IND RES INST
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