The application relates to a CePO4@RuO2@Cu-MOF heteronano-wire and a preparation method thereof and application thereof in selective oxidation synthesis of
vitamin K intermediates, and belongs to the technical field of nano functional materials and
catalysis. The CePO4@RuO2@Cu-MOF heteronano-wire is a one-dimensional ternary structure, the one-dimensional CePO4 nano-wire is used as a core base material, the middle layer is RuO2 nano active sites in-situ heterogeneously grown, and the outer layer is a Cu-MOF porous shell layer in-situ grown; a continuous and firm hetero-interface is formed among the three phases. The material obtained by the application exhibits super-high product selectivity, excellent catalytic activity and super-long cycle stability in the reaction of catalyzing selective oxidation of 2-methylnaphthalene to prepare a
vitamin K key intermediate through the channel limiting effect and interface electronic
coupling effect of the outer layer Cu-MOF.