The invention discloses a silk anti-wrinkle non-ironing finishing agent, which comprises, by weight, 10-30 parts of a melamine resin, 20-40 parts of a formaldehyde resin, 4-6 parts of isopropyl alcohol, 6-12 parts of 2-hydroxyethyl methacrylate, 10-18 parts of magnesium chloride, 4-8 parts of a glycerin rosin resin, 4-8 parts of zinc nitrate hexahydrate, 10-20 parts of benzoyl peroxide, 8-16 partsof polydivinyl acetylene, 10-16 parts of naphthenic acid, 4-12 parts of ammonium citrate, 2-8 parts of glacial acetic acid, 6-16 parts of acrylamide, 4-8 parts of methyl methacrylate, 5-15 parts of vinyl chloride vinyl ester, and 100-140 parts of deionized water. According to the present invention, the production of the silk anti-wrinkle non-ironing finishing agent is simple, the used productionraw materials are non-toxic, and the fabric treated by the silk anti-wrinkle non-ironing finishing agent has characteristics of wrinkle resistance, shrinkage resistance, good shaping effect, no ironing, starching, fullness, no stain, and the like.