Polyurethane caulking material for expansion joints of ballastless track of high speed railway

A technology of caulking material and ballastless track, applied in the field of building materials, can solve the problems of high tensile modulus, difficult curing, high sensitivity, etc., achieve moderate molecular chain length and functionality, improve bonding performance and durability Good performance, low temperature curing performance

Active Publication Date: 2014-08-20
RAILWAY ENG RES INST CHINA ACADEMY OF RAILWAY SCI +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current market lacks polyurethane caulking materials designed according to the actual needs of high-speed railway ballastless track, and the existing products used in high-speed railway ballastless track expansion joints still have the following problems: (1) the joint between high-speed railway ballastless track structure The deformation characteristics do not match, the displacement capacity is low, and the tensile modulus is high, which cannot meet the requirements of 50LM sealant, and it is easy to have problems of separation and cracking during use
(2) The durability and fatigue resistance are poor, and it is easy to be damaged under the action of temperature force and train dynamic load, and it is prone to problems such as peeling, pulverization and cracking under the sun for a long time, and loses the waterproof and sealing function.
(3) It is highly sensitive to temperature and humidity. It is easy to foam when the air humidity is high, and it is difficult to cure when it is below 5°C.
(4) When stored at low temperature, solid chain-extending cross-linking agents such as MOCA are easy to precipitate
Moreover, using tap water as a chain extender, when the colloid perfusion thickness is deep, it is easy to foam and difficult to control
At the same time, the cost of aliphatic isocyanate and hydroxyl silicone oil is high, especially aliphatic isocyanate, its price is generally more than twice that of commonly used aromatic isocyanate

Method used

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  • Polyurethane caulking material for expansion joints of ballastless track of high speed railway

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Composition of polyurethane caulking material:

[0036] Component A: 20 parts of modified TDI and 80 parts of polyoxyethylene-propylene oxide copolyol, a prepolymer with an isocyanate group content of 2.5%, 5 parts of dibutyl phthalate, and dioctyl phthalate 5 parts of ester, 1 part of calcium oxide, parts of titanium dioxide, 2 parts of light calcium carbonate, 1 part of carbon black, 0.5 parts of diacetone alcohol, 0.5 parts of dipropylene glycol, 0.5 parts of silane coupling agent A-186, silane coupling 0.5 part of agent A-1310, 0.5 part of oxazole water remover, 0.5 part of p-toluenesulfonyl isocyanate;

[0037] Part B is composed of the following raw materials in parts by weight: 5 parts of oleochemical polyol, 5 parts of modified epoxy resin, 1 part of butyl acetate, 2 parts of chlorinated paraffin, 2 parts of talcum powder, 3 parts of silicon micropowder, defoaming Agent BYK-070 0.5 parts, light stabilizer 0.05 parts, antioxidant 0.02 parts, hydrolysis stabilize...

Embodiment 2

[0040] Composition of polyurethane caulking material:

[0041] Component A: 30 parts of modified TDI, 20 parts of polyoxyethylene-oxypropylene copolyol and 50 parts of tetrahydrofuran-oxypropylene copolyether polyol, a prepolymer with an isocyanate group content of 0.5%, phthalic acid di 20 parts of butyl ester, 50 parts of dioctyl phthalate, 10 parts of chlorinated paraffin, 100 parts of light calcium carbonate, 30 parts of talcum powder, 10 parts of montmorillonite, 5 parts of cement, 1 part of calcium hydroxide, charcoal 4 parts of black, 10 parts of diacetone alcohol, 10 parts of dichloromethane, 2 parts of silane coupling agent A-1310, 3 parts of silane coupling agent A-LINK35, 6 parts of nano calcium carbonate, 4 parts of fumed silica, 3 parts of toluenesulfonyl isocyanate;

[0042] Part B is composed of the following raw materials in parts by weight: 15 parts of modified vegetable oil polyol, 5 parts of urethane polyol, 2 parts of dipropylene glycol, 3 parts of butyl a...

Embodiment 3

[0045] Composition of polyurethane caulking material:

[0046] Component A: 35 parts of modified MDI, 60 parts of polyoxyethylene-propylene oxide copolyol and 20 parts of polyacrylate polyol, a prepolymer with an isocyanate group content of 1.5%, 100 parts of dibutyl phthalate 50 parts of chlorinated paraffin, 50 parts of silica powder, 10 parts of montmorillonite, 5.5 parts of cement, 5 parts of titanium dioxide, 2 parts of calcium oxide, 5 parts of carbon black, 5 parts of dipropylene glycol, 5.5 parts of dichloromethane , 1 part of silane coupling agent A-1861, 352 parts of silane coupling agent A-LINK, 4 parts of nano calcium carbonate, 1 part of hydrogenated castor oil, 2 parts of oxazole water remover;

[0047] Part B consists of the following raw materials in parts by weight: 5 parts of modified epoxy resin, 10 parts of modified vegetable oil polyol, 3 parts of diacetone alcohol, 10 parts of dioctyl phthalate, 10 parts of light calcium carbonate, Talc powder 7.5 parts,...

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Abstract

A polyurethane caulking material for expansion joints of a ballastless track of a high speed railway is disclosed. The caulking material is prepared from two parts A and B. the part A is composed of the following raw materials, by weight, 100 parts of isocyanate and its prepolymer, 10-150 parts of a plasticizer, 5-150 parts of a solid filler, 1-20 parts of a diluents, 1-5 parts of an adhesion promoter, 0-10 parts of a thixotropic agent and 1-3 parts of a water-removal agent. The part B is composed of the following raw materials, by weight, 10-20 parts of modified polyhydric alcohol, 1-5 parts of a diluent, 2-30 parts of a plasticizer, 5-30 parts of a solid filler, 0-5 parts of a thixotropic agent, 0.5-2 parts of an antifoaming agent, 0.1-1 part of an anti-aging agent and 0-0.01 part of a catalyst. The mass ratio of the part A to the part B is 4:1-10:1. The polyurethane caulking material has advantages of good low-temperature curing performance, high displacement capability, low tensile modulus, good bond property and excellent endurance quality and fatigue resistance, and is suitable for expansion joints of a ballastless track of a high speed railway as well as expansion joints of roads and airfield runways.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a polyurethane caulking material used for expansion joints of high-speed railway ballastless tracks. Background technique [0002] In the ballastless track structure of high-speed railway, the base slab and track bed slab are long-line continuous pouring structures. In order to adapt to the deformation of the concrete structure at different temperatures, it is often necessary to set expansion joints at a certain distance. There are a large number of joints, all of which require the use of caulking materials that can withstand changes in joint displacement to prevent moisture, debris, etc. from entering the joint. [0003] The displacement of expansion joints set on the base plate and ballast bed plate of the long continuous pouring structure is very large. Taking the base plate of CRTS III slab ballastless track as an example, the displacement of expansion joints mai...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08K13/02C08K5/12C08K5/02C08K3/22C08K3/26C08K3/04C08K3/34C08G18/66C08G18/10C08G18/12
Inventor 李化建易忠来靳昊谭盐宾谢永江
Owner RAILWAY ENG RES INST CHINA ACADEMY OF RAILWAY SCI
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