The invention discloses a
perylene tetracarboxylic
diimide copolymer containing a dithieno
quinoxaline unit as well as a preparation method and application thereof. The
copolymer is shown in the specification. The preparation method comprises adding a
perylene tetracarboxylic
diimide dibromide and a 6,9-bis(tributyl
tin)-dithieno[3,2-f:2',3'-h]
quinoxaline derivative in an
organic solvent, adding a catalyst, carrying out Stille
coupling reaction at the temperature of 50-120 DEG C for 24-72 hours, and refining to obtain the
copolymer. The copolymer disclosed by the invention can be applied to manufacture of
polymer solar cell devices, organic
field effect transistors, organic electroluminescent devices, organic
light storage devices, organic nonlinear materials or
organic laser devices. Thecopolymer disclosed by the invention has the advantages of good
solubility, strong light absorbency and excellent charge transfer performance, the absorption range of the copolymer can extend to a near
infrared region, and the
sunlight utilization rate can be increased; and the preparation method has a simple synthesis
route and a low process requirement.