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Thermochromic laminated glass and processing technology thereof

A laminated glass, thermochromic technology, applied in glass/slag layered products, coatings, layered products, etc., can solve the problems of small effect, poor high temperature resistance, low temperature resistance and high production cost

Active Publication Date: 2019-05-17
河源市东方硅源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Electrochromism is a phenomenon in which the color-changing material undergoes a stable and reversible color change under the action of an applied current or electric field using optical properties such as light reflectance, transmittance, and absorption rate. Electrochromic glass has good chemical and The mechanical stability realizes the rapid transition between the transparent state and the opaque state, and the transition speed is within a few seconds, but the electrochromic interlayer belongs to the liquid crystal dimming film, and the liquid crystal is relatively expensive, and the production cost is high. Due to the difficulty in the production process between ordinary glass and the short service life of electrochromic glass, it is not conducive to the popularization and use of color-changing glass. The liquid crystal dimming film is firmly bonded between two pieces of ordinary float glass to form a
[0004] Thermochromic glass means that the color of the glass changes with the temperature of the surrounding environment. When the temperature is lower than the critical value, the glass is the same as ordinary glass and presents a transparent state. As the external environment increases, when the temperature is higher than the critical value, The color of the glass gradually becomes darker to block the entry of external sunlight. However, in the prior art, ordinary glass is sandwiched with a layer of thermochromic material. , the process of this adjustment method is slow, and the active adjustment function cannot be realized under low temperature conditions, and it has little effect on ultraviolet light and infrared light, and although the thermochromic laminated glass has a blocking effect on noise, the effect is poor, and people still It is deeply disturbed by noise and affects daily rest. The interlayer in thermochromic laminated glass is prone to bubbles during the production process. The interlayer film coated on the glass is not easy to disperse, resulting in uneven application, and poor high temperature and low temperature resistance. , and will produce static electricity, causing harm to the human body

Method used

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  • Thermochromic laminated glass and processing technology thereof
  • Thermochromic laminated glass and processing technology thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] A thermochromic laminated glass, the thermochromic laminated glass is calculated in parts by weight:

[0055] Two pieces of ordinary glass, 80 parts of PVB film, 0.3 parts of vanadium dioxide powder, 12.5 parts of dioctyl phthalate, 1 part of vinyl triethoxy silane, 50 parts of polydimethylsiloxane grafted polyethylene Parts, 3 parts of wollastonite, 0.3 parts of titanium dioxide powder, 0.02 parts of iron oxide powder, 0.01 parts of copper oxide powder, 0.02 parts of nickel oxide powder.

[0056] A process for processing thermochromic laminated glass. The thermochromic laminated glass includes the following steps:

[0057] (1) Preparation of silicone polymer modified polyethylene;

[0058] (A) Heat 2 parts by weight of organosilicon polymer and 10 parts of n-heptane in a heating furnace to 50°C;

[0059] (B) Stir the substances in step (a) to a paste;

[0060] (C) In step (b), continue to add 1.5 parts by weight of silicone polymer and 5 parts of polyethylene to knead in a knead...

Embodiment 2

[0076] A thermochromic laminated glass, the thermochromic laminated glass is calculated in parts by weight:

[0077] Two pieces of ordinary glass, 100 parts of EVA film, 2 parts of vanadium dioxide powder, 15 parts of diisooctyl phthalate, 3 parts of vinyl trisilane, 80 parts of polymethylvinylsiloxane grafted polyethylene , 16 parts of calcium carbonate, 1 part of titanium dioxide powder, 1 part of iron oxide powder, 1 part of copper oxide powder, 1 part of nickel oxide powder.

[0078] A process for processing thermochromic laminated glass. The thermochromic laminated glass includes the following steps:

[0079] (1) Preparation of silicone polymer modified polyethylene;

[0080] (A) Heat 2 parts by weight of organosilicon polymer and 10 parts of n-heptane in a heating furnace to 50°C;

[0081] (B) Stir the substances in step (a) to a paste;

[0082] (C) In step (b), continue to add 1.5 parts by weight of silicone polymer and 5 parts of polyethylene to knead in a kneader;

[0083] (D) D...

Embodiment 3

[0098] A thermochromic laminated glass, the thermochromic laminated glass is calculated in parts by weight:

[0099] Two pieces of ordinary glass, 85 parts of POE film, 1 part of vanadium dioxide powder, 0.5 parts of titanium dioxide powder, 13 parts of dibutyl phthalate, 1.5 parts of γ-propyl methacrylate trimethoxysilane, iron oxide Powder 0.3 parts, copper oxide powder 0.3 parts, nickel oxide powder 0.3 parts, polydimethylsiloxane grafted polyethylene 60 parts, talc powder 5 parts.

[0100] A process for processing thermochromic laminated glass. The thermochromic laminated glass includes the following steps:

[0101] (1) Preparation of silicone polymer modified polyethylene;

[0102] (A) Heat 2 parts by weight of organosilicon polymer and 10 parts of n-heptane in a heating furnace to 50°C;

[0103] (B) Stir the substances in step (a) to a paste;

[0104] (C) In step (b), continue to add 1.5 parts by weight of silicone polymer and 5 parts of polyethylene to knead in a kneader;

[0105]...

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Abstract

The invention discloses thermochromic laminated glass and a processing technology thereof. A formula of the thermochromic laminated glass contains a glass substrate, a polymer intermediate layer, titanium dioxide powder, vanadium dioxide powder, a plasticizer, a coupling agent, organosilicone polymer modified polyethylene, a noise-absorbing material, iron oxide powder, copper oxide powder and nickel oxide powder, and the processing technology of the thermochromic laminated glass is further included. A thermochromic glue sheet is prepared through fusion of the polymer intermediate layer, the titanium dioxide powder, the vanadium dioxide powder, the plasticizer, the coupling agent, the organosilicone polymer modified polyethylene, the noise-absorbing material, the iron oxide powder, the copper oxide powder and the nickel oxide powder, then the thermochromic glue sheet and the glass substrate are treated through a high temperature and high pressure technology, thus the thermochromic laminated glass is prepared, the basic structure of laminated glass in the prior art is not changed, operation is easy, the thermochromic laminated glass has no harm to a human body, the high-temperature resistance and low-temperature resistance characteristics are improved to a great extent, the mechanical properties and chemical properties are improved, noise is reduced, the light transmittance of ultraviolet light and infrared light is decreased, the sleep quality of people is improved, and harm of ultraviolet rays to the human body is prevented.

Description

Technical field [0001] The invention relates to the technical field of glass, in particular to a thermochromic laminated glass and its processing technology. Background technique [0002] Ultraviolet rays UV-B in the sun has serious harmful effects on human health. The potential dangers include causing and aggravating eye diseases, skin cancer and infectious diseases. Studies have shown that long-term exposure to strong ultraviolet radiation can cause DNA changes in cells, the function of the human immune system declines, and the human body’s ability to resist diseases has been reduced. Anti-ultraviolet radiation has long attracted people’s attention. At the same time, the penetration rate of infrared rays in sunlight is large. Under the conditions of sunlight, infrared rays will light It can be converted into heat energy. In the hot summer, the indoor temperature is increased. In order to increase the indoor anti-ultraviolet function and infrared radiation, people have begun to ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C27/10C09J129/04C09J201/00C09J123/08C09J11/06C09J11/04
CPCB29C41/02B29C65/02B29C66/45B29C66/7311B29C66/7465B29K2023/06B29K2105/0005B29K2105/0047B29L2007/002B29L2009/00B32B7/023B32B17/10B32B17/1055B32B17/10633B32B17/10678B32B17/10788B32B17/10798B32B17/10871B32B17/10889B32B17/10972B32B27/18B32B27/22B32B27/306B32B27/32B32B33/00B32B2307/10B32B2307/21B32B2307/306B32B2307/71B32B2307/714B32B2307/746C08G81/024C08K2003/2241C08K2003/2248C08K2003/2272C08K2003/2293C08L2205/025C09J7/10C09J7/30C09J11/04C09J11/06C09J11/08C09J123/0815C09J123/0853C09J129/14C09J187/005B32B2329/06B32B2323/00C08L87/005C08K13/02C08K3/22C08K5/12
Inventor 高路生
Owner 河源市东方硅源科技有限公司
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