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Environmentally-friendly epoxy modified acrylic coating for hardware parts, and preparation method thereof

An epoxy-modified, environmentally friendly coating technology, applied in anti-corrosion coatings, fire-resistant coatings, conductive coatings, etc., can solve the problems of poor water resistance, alkali resistance and weather resistance, easy to be corroded, and become brittle, and achieve a large specific surface area , Good UV shielding performance, high chemical activity effect

Inactive Publication Date: 2020-02-11
湖南太子化工涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hardware and hardware parts are mostly metal products, which are easily corroded in a humid atmosphere or in a special working environment, resulting in damage to the hardware parts and, in serious cases, damage to the entire machine. Therefore, anti-corrosion coating protection for hardware parts is quite necessary
However, acrylic paint is sticky at high temperature, brittle at low temperature, and has poor water resistance, alkali resistance and weather resistance, and its wide application has been restricted to a certain extent.

Method used

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  • Environmentally-friendly epoxy modified acrylic coating for hardware parts, and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] An environmentally friendly coating for epoxy-modified acrylic hardware parts, comprising the following raw materials in parts by weight: 75 parts of epoxy-modified acrylic resin, 0.8 part of sodium methylene bis-naphthalene sulfonate, 0.5 part of propylene glycol phenyl ether, hydroxypropyl methyl 1.2 parts of cellulose, 1.6 parts of dimethylethanolamine, 4.5 parts of barium sulfate, 2.4 parts of calcium oxide, 1.5 parts of nano zinc oxide, 1.4 parts of graphene oxide, 12 parts of water; epoxy modified acrylic resin is made of epoxy resin E- 44. Butyl acrylate, methacrylic acid, and styrene are prepared by ring-opening esterification. The weight parts of each raw material of epoxy-modified acrylic resin are: epoxy resin E-4418 parts, butyl acrylate 18 parts, methacrylic acid 15 parts, 20 parts of styrene, 5 parts of octylphenol polyoxyethylene ether, 2.5 parts of sodium dodecyl sulfate, 0.8 parts of ammonium persulfate, and 0.3 parts of sodium bicarbonate.

[0043] A p...

Embodiment 2

[0050] An epoxy-modified acrylic acid environmental protection coating for hardware parts, comprising the following raw materials in parts by weight: 60 parts of epoxy-modified acrylic resin, 0.6 part of sodium methylene bis-naphthalene sulfonate, 1 part of propylene glycol phenyl ether, hydroxypropyl methyl 1.5 parts of cellulose, 2 parts of dimethylethanolamine, 3.5 parts of barium sulfate, 2.2 parts of calcium oxide, 0.6 parts of nano-zinc oxide, 0.8 parts of graphene oxide, 15 parts of water; epoxy modified acrylic resin is composed of epoxy resin E- 51. Butyl acrylate, methacrylic acid, and styrene are prepared by ring-opening esterification. The parts by weight of the raw materials of epoxy-modified acrylic resin are: epoxy resin E-5120 parts, butyl acrylate 10 parts, methacrylic acid 15 parts, 25 parts of styrene, 6 parts of octylphenol polyoxyethylene ether, 2 parts of sodium dodecyl sulfate, 1.5 parts of potassium persulfate, and 0.5 parts of sodium bicarbonate.

[00...

Embodiment 3

[0058] An epoxy-modified acrylic acid environmental protection coating for hardware parts, comprising the following raw materials in parts by weight: 75 parts of epoxy-modified acrylic resin, 0.5 part of sodium methylene bis-naphthalene sulfonate, 0.8 part of propylene glycol phenyl ether, hydroxypropyl methyl 1.5 parts of cellulose, 2 parts of dimethylethanolamine, 5 parts of barium sulfate, 2.5 parts of calcium oxide, 1.8 parts of nano-zinc oxide, 2 parts of graphene oxide, 12 parts of water; epoxy modified acrylic resin is made of epoxy resin E- 44. Butyl acrylate, methacrylic acid, and styrene are prepared by ring-opening esterification. The parts by weight of each raw material of epoxy-modified acrylic resin are: epoxy resin E-4415 parts, butyl acrylate 15 parts, methacrylic acid 10 parts, 20 parts of styrene, 6 parts of octylphenol polyoxyethylene ether, 3 parts of sodium dodecylsulfonate, 1.2 parts of ammonium persulfate, and 0.2 parts of sodium bicarbonate.

[0059] A ...

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Abstract

The invention provides an environmentally-friendly epoxy modified acrylic coating for hardware parts, and a preparation method thereof. The coating comprises, by weight, 60-80 parts of epoxy modifiedacrylic resin, 0.5-1 part of sodium methylene dinaphthalene sulfonate, 0.5-1 part of propylene glycol phenyl ether, 1-2 parts of hydroxypropyl methyl cellulose, 1-2 parts of dimethylethanolamine, 3-6parts of barium sulfate, 2-3 parts of calcium oxide, 1-2 parts of nanometer zinc oxide, 1-2 parts of graphene oxide and 10-15 parts of water. The epoxy modified acrylic resin is obtained through a ring-opening esterification reaction of an epoxy resin and an acrylic monomer, so the problems of sticking at a high temperature, high brittleness at a low temperature, poor water resistance, poor alkaliresistance and poor weather resistance of an acrylic coating are solved; and the graphene oxide and nanometer zinc oxide are added, so that the mechanical properties and the corrosion resistance of the coating are effectively improved.

Description

technical field [0001] The invention relates to the technical field of acrylic paints, in particular to an epoxy-modified acrylic hardware spare parts environment-friendly paint and a preparation method thereof. Background technique [0002] Hardware spare parts refer to machine parts or components made of hardware, as well as some small hardware products. It can be used alone or as an auxiliary tool. Such as hardware tools, hardware parts, daily hardware, construction hardware and security supplies, etc. Most hardware products are not final consumer goods. Instead, it is used as ancillary products, semi-finished products, and tools used in the production process for industrial manufacturing. Only a small part of daily hardware products (accessories) are tools and consumer goods necessary for people's lives. Hardware and hardware parts are mostly metal products, which are easily corroded in a humid atmosphere or in a special working environment, resulting in damage to th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D151/08C09D5/08C09D7/61C09D5/24C09D5/18C09D5/14C08F283/10C08F220/18C08F220/06C08F212/08
CPCC08F283/10C08K2003/2206C08K2003/2296C08K2003/3045C08K2201/011C08L2201/02C08L2201/08C09D5/08C09D5/14C09D5/18C09D5/24C09D151/08C09D7/61C08L1/284C08K13/02C08K3/30C08K3/22C08K3/042C08F220/06C08F212/08
Inventor 刘骏
Owner 湖南太子化工涂料有限公司
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