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Silicon-carbon composite negative electrode material, negative electrode plate, preparation method thereof and lithium-ion battery

A negative electrode material, silicon carbon composite technology, applied in batteries, negative electrodes, electrode manufacturing and other directions, can solve the problems of volume expansion, poor cycle performance of lithium ion batteries, electrochemical performance and cycle life to be improved, etc.

Active Publication Date: 2020-08-07
厦门高容纳米新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the severe volume expansion (volume expansion of about 400%) of silicon materials during charge and discharge, the cycle performance of lithium-ion batteries is very poor.
In order to alleviate the volume expansion of silicon materials, silicon-carbon composite materials have been developed, and carbon is used to coat and modify silicon-based materials. However, the electrochemical performance and cycle life of existing silicon-carbon composite materials still need to be improved.

Method used

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  • Silicon-carbon composite negative electrode material, negative electrode plate, preparation method thereof and lithium-ion battery
  • Silicon-carbon composite negative electrode material, negative electrode plate, preparation method thereof and lithium-ion battery

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preparation example Construction

[0034] The present invention also provides a method for preparing a negative electrode sheet. The method comprises uniformly mixing the negative electrode material with a conductive agent, a binder and a solvent to obtain an electrode slurry, and coating the electrode slurry on the surface of a current collector, and drying Dry, wherein, the negative electrode material is the above-mentioned silicon-carbon composite negative electrode material.

[0035] The main improvement of the preparation method of the negative electrode sheet provided by the present invention is to adopt a new negative electrode material, and the specific types of conductive agent, binder and solvent and their consumption with the negative electrode material and the like can be compared with the existing ones. The technique is the same. For example, specific examples of the conductive agent include, but are not limited to: at least one of super carbon black, graphene, carbon fiber and graphite. Specific ...

Embodiment 1

[0042] S1. Mix 100mL ethanol and 20mL water and heat to 60°C, add 2.5mL ammonia water (concentration: 5wt%, the same below) and 0.5mL ethylenediamine and mix evenly, then add 1g 3-aminophenol, 2mL formaldehyde and 4mL silicic acid Ethyl ester was vigorously stirred at 30rpm for 6 hours to form a precipitated product, which was centrifuged and dried at 60°C for 3 hours to obtain a silica / phenolic compound with a fractal structure.

[0043] S2. Take 2g of the above-mentioned silica / phenolic compound and 2g of magnesium powder, grind and mix them evenly, and put them into a tube furnace. The tube furnace is protected by argon gas containing 1% hydrogen, and the tube furnace is heated to 350°C. The heat preservation reaction is carried out for 10 hours, and the composite material powder of silicon and amorphous carbon having a fractal structure is obtained from the reaction. The composite material powder is taken out, treated with dilute hydrochloric acid to remove the remaining u...

Embodiment 2

[0046] S1. Mix 90mL of ethanol and 10mL of water and heat to 80°C, add 2mL of ammonia water and 0.3mL of ethylenediamine and mix well, then add 1.5g of 3-aminophenol, 3.2mL of formaldehyde and 6mL of ethyl silicate, and stir vigorously at 150rpm After 4 hours, the reaction produced a precipitate product, which was centrifuged, and the obtained solid product was dried at 90° C. for 1 hour to obtain a silica / phenolic compound with a fractal structure.

[0047] S2: Take 2 g of the above-mentioned silica / phenolic compound and put it into a tube furnace. The tube furnace is protected by argon gas containing 1% hydrogen, and the tube furnace is heated to 1000 ° C for 0.5 h. The roasted product is cooled to room temperature, crushed and ground and mixed with 3g of aluminum powder evenly, put into the tube furnace again, and the tube furnace is fed with argon gas protection containing 1% hydrogen, and the tube furnace is heated to 500°C for roasting for 6 Hours, the reaction yields a ...

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Abstract

The invention belongs to the field of new energy materials, and relates to a silicon-carbon composite negative electrode material, a negative electrode plate, a preparation method thereof and a lithium-ion battery. The preparation method of the silicon-carbon composite negative electrode material comprises the following steps: S1, dispersing phenol and / or aminophenol, formaldehyde and a silicon precursor material into an alcohol-amine mixed aqueous solution, violently stirring and reacting at 20-90 DEG C for at least 20 minutes, carrying out solid-liquid separation, and drying to obtain a silicon dioxide / phenolic aldehyde compound with a fractal structure; and S2, roasting the silicon dioxide / phenolic aldehyde compound in the presence of magnesium powder and / or aluminum powder to obtain the silicon-carbon composite material with the fractal structure. When the silicon-carbon composite material is used as a lithium-ion battery negative electrode material, the failure caused by volume change in the charging and discharging process can be well overcome, a good conductive network is maintained, the volume expansion is reduced, the first reversible capacity and the first coulombic efficiency are improved, the first cycle capacity loss is reduced, and the cycle stability is improved.

Description

technical field [0001] The invention belongs to the field of new energy materials, and in particular relates to a silicon-carbon composite negative electrode material, a negative electrode sheet, a preparation method thereof, and a lithium ion battery. Background technique [0002] At present, with the development of the new energy industry and the intensification of environmental pollution, the development of electric vehicles is becoming more and more rapid, and lithium-ion batteries with high capacity, high power and long cycle life have become urgently important. Lithium-ion batteries are the core of new energy vehicles and energy storage technologies at this stage, and the electrochemical performance of lithium-ion batteries mainly depends on the positive and negative electrodes of the battery. The key to lithium-ion batteries. Cathode materials have been extensively studied, and anode materials have also received more and more attention. Conventional lithium-ion batt...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/583H01M4/1395H01M4/1393H01M4/134H01M4/133H01M4/04H01M10/0525
CPCH01M4/364H01M4/386H01M4/583H01M4/1395H01M4/1393H01M4/134H01M4/133H01M4/0471H01M10/0525H01M2220/20H01M2004/027Y02E60/10
Inventor 蒋玉雄
Owner 厦门高容纳米新材料科技有限公司
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