Preparation method of copper-based nano solar battery material

A solar cell, nanotechnology, applied in the directions of nanotechnology, nanotechnology, chemical instruments and methods, etc., can solve problems such as unfavorable large-scale industrial production, unfavorable solar cell light absorption, expensive high-vacuum system, etc., and achieves less harsh reaction conditions. , The yield is pollution-free, and the monodispersity is good.

Inactive Publication Date: 2013-05-22
NANJING UNIV OF TECH
View PDF4 Cites 16 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The trivalent magnetic iron atoms replace the atoms of III, but the d-type conduction band makes the band gap drop sharply to 0.5~0.6eV
[0010] The preparation methods of copper-based solar cell nanomaterials reported in the literature mainly include gas-phase methods and liquid-phase methods, and gas-phase methods mainly include Spray Pyrolysis, RF Sputtering, and v...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of copper-based nano solar battery material
  • Preparation method of copper-based nano solar battery material
  • Preparation method of copper-based nano solar battery material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] 2mmolCuCl 2 and 2mmolInCl 3 4H 2 O The two powders were mixed in a one-necked flask, and then 10mmol of sodium oleate was added, followed by 10ml of water, 15ml of ethanol and 30ml of n-hexane. It was heated to reflux at 60° C. for 4 hours to obtain a separated two-phase liquid. After separating the layered liquid with a separatory funnel, take the upper oil phase and evaporate ethanol and n-hexane at 70°C, and then evaporate the remaining water at 110°C to obtain a waxy mixture of copper oleate and indium oleate.

[0039] Take 30ml of oleylamine and 5ml of n-dodecanethiol and mix them in a three-necked flask filled with inert gas, and heat to 290°C. Take 2g of the synthesized mixture of copper oleate and indium oleate and completely dissolve it in 2ml of oleylamine at 150°C, and inject 0.4ml of the mixture into a flask, and keep it at 290°C for 25min to obtain a black solution. Cool to room temperature, wash with ethanol and n-hexane with a volume ratio of 1:3, cen...

Embodiment 2

[0043] 2mmolCuCl 2 and 2mmolInCl 3 4H 2 O The two powders were mixed in a one-necked flask, and then 10mmol of sodium oleate was added, followed by 10ml of water, 15ml of ethanol and 30ml of n-hexane. It was heated to reflux at 60° C. for 4 hours to obtain a separated two-phase liquid. After separating the layered liquid with a separatory funnel, take the upper oil phase and evaporate ethanol and n-hexane at 70°C, and then evaporate the remaining water at 110°C to obtain a waxy mixture of copper oleate and indium oleate.

[0044] Take 20ml of oleylamine, 10ml of oleic acid and 5ml of n-dodecanethiol and mix them in a three-necked flask filled with inert gas, and heat to 290°C. Take 2g of the synthesized mixture of copper oleate and indium oleate and completely dissolve it in 2ml of oleylamine at 150°C, and inject 0.4ml of the mixture into a flask, and keep it at 290°C for 5min to obtain a black solution. Cool to room temperature, wash with ethanol and chloroform at a volum...

Embodiment 3

[0048] 2mmolCuCl 2 and 2mmolInCl 3 4H 2 O The two powders were mixed in a one-necked flask, and then 10mmol of sodium oleate was added, followed by 10ml of water, 15ml of ethanol and 30ml of n-hexane. It was heated to reflux at 60° C. for 4 hours to obtain a separated two-phase liquid. After separating the layered liquid with a separatory funnel, take the upper oil phase and evaporate ethanol and n-hexane at 70°C, and then evaporate the remaining water at 110°C to obtain a waxy mixture of copper oleate and indium oleate.

[0049] Take 20ml of oleylamine, 10ml of 1-octadecene and 5ml of n-dodecanethiol and mix them in a three-necked flask filled with inert gas, and heat to 290°C. Take 2g of the synthesized mixture of copper oleate and indium oleate and completely dissolve it in 2ml of oleylamine at 150°C, and inject 0.4ml of the mixture into a flask, and keep it at 290°C for 25min to obtain a black solution. Cool to room temperature, wash with ethanol and acetone at a volum...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Diameteraaaaaaaaaa
Heightaaaaaaaaaa
Diameteraaaaaaaaaa
Login to view more

Abstract

The invention relates to a preparation method of a copper-based nano solar battery material, which belongs to the preparation technique of semiconductor nano solar battery materials. A metallic compound is taken as a precursor, mercaptan, elemental sulfur, elemental selenium and the like as sulfur raw materials, and oleylamine, oleic acid, 1-octadecene and TOPO (Tri-Octyl-Phosphine Oxide) as a main high-boiling-point solvent. By adopting a thermal decomposition method, the copper-based nano solar battery material which is different in morphology, good in crystallinity degree, good in monodispersity, controllable in phase structure and adjustable in optical property is prepared under unharsh reaction condition, thus basis is established for application and industrial production of the high-quality nano copper-based solar material in the aspects of solar battery preparation and photocatalyst design. The copper-based nano solar battery material has the characteristics of controllable product property, high quality, simple production process, environmental-friendliness and the like, and is easy to industry.

Description

technical field [0001] The invention relates to a method for preparing a copper-based nanometer solar cell material, which belongs to the field of new energy materials, and in particular to a method for preparing high-quality monodisperse nanocrystals using a metal compound as a precursor by using a high-temperature organic solvent pyrolysis method. Background technique [0002] Solar energy is an inexhaustible clean energy, and it is the ultimate energy to replace traditional unsustainable fossil energy. Solar cells are a renewable solar power generation method based on the photovoltaic effect, which does not produce greenhouse gases such as carbon dioxide during the power generation process, and is an environmentally friendly power generation method. At present, monocrystalline silicon and polycrystalline silicon solar cells have been mass-produced on a large scale. Due to the low absorption coefficient of silicon, a certain thickness is required, and materials will be add...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C01G15/00B82Y30/00
Inventor 暴宁钟邱新民高凌沈丽明
Owner NANJING UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap