Method for preparing carbon material at low temperature and co-producing fertilizer

A carbon material and fertilizer technology, applied in the field of low-temperature preparation of carbon material co-production fertilizer, can solve the problems of low activation rate, equipment corrosion, complex treatment process, etc., and achieve the effects of low reaction conditions, reduced environmental pressure, and high application value

Inactive Publication Date: 2017-12-12
SICHUAN UNIV
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Problems solved by technology

Compared with the two methods, the energy consumption of physical activation is high, the activation rate is low, and the yield is low
In addition, a large amount of chemical reagents are used in the chemical activation process, which not only causes corrosion of equipment, but also complicates the subsequent treatment process. After activated carbon is activated, it needs to be neutralized and washed. In order to meet the requirements of environmental protection and emission, the energy consumption is high, which increases the preparation cost of activated carbon to varying degrees and hinders the application of activated carbon.
Although the current hydrothermal method can make the reaction proceed in a closed environment, there are problems such as uniform mixing of materials, high energy consumption and difficult treatment of carbon-rich waste liquid.

Method used

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  • Method for preparing carbon material at low temperature and co-producing fertilizer
  • Method for preparing carbon material at low temperature and co-producing fertilizer

Examples

Experimental program
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Effect test

Embodiment 1

[0022] Using microbial action and hydrothermal method to prepare coal-like carbon materials from tobacco stalks, put 2 g of tobacco stalk powder, 20 mL of deionized water and 5 mL of microbial culture solution into a 50 mL reactor and seal it. After 5 hours of biochemical reaction Then react at 150 °C for 3 h, filter and wash the reaction product, and dry the filter cake at 100 °C for 10 h to obtain a coal-like carbon material. Corresponding pH value or composition), used as fertilizer for greening grass. Combustion performance analysis of the obtained carbon material shows that its combustion activation energy is about 50% higher than that of the raw material. The microorganisms produced in the early stage of the reaction enter the carbon material or waste liquid during the later hydrothermal reaction process, reducing the harm of microorganisms to the environment after the reaction, and realizing the integration of growth, reproduction, efficient utilization and transformati...

Embodiment 2

[0024] Preparation of activated carbon and ammonium phosphate fertilizer from magnolia bark waste by hydrothermal method. Magnolia officinalis powder and activator (mass content of 20% H 3 PO 4 ) into the enamel reaction kettle at a mass ratio of 1:1, and reacted hydrothermally at 200 °C for 24 h. After the reaction, the reaction product solution was filtered to obtain a carbon filter cake and the first filtrate. Activated in an argon atmosphere for 2 h (without adding other activators), the product was washed with water until neutral, and the filtered filter cake was dried to obtain activated carbon. After mixing the washing water and the two filtrates, adjust the pH value to 4.0 ~ 4.5 with ammonia water. Concentrated granulation can be nitrogen-phosphorus binary compound fertilizer based on ammonium dihydrogen phosphate; adjust the pH value to 7.8 ~ 8.2, concentrated granulation can be based on diammonium hydrogen phosphate binary nitrogen-phosphorus compound fertilizer. T...

Embodiment 3

[0026] Activated carbon was prepared from waste walnut shells by alcohol thermal method. Put 3g of walnut shell powder, 10mL of ethanol and 15mL of water into a reaction kettle made of Hastelloy C, and react at 300 ℃ for 4~7 h. After the reaction, the product solution Filter to obtain carbon material filter cake and the first filtrate, filter cake and NH 4 h 2 PO 4After mixing, it is activated at 700°C for 3 hours to obtain activated carbon, which is washed to nearly neutral and filtered again to obtain activated carbon filter cake and the second filtrate. The activated carbon filter cake is used for wastewater treatment, and the adsorption capacity of methylene blue is higher than that of walnut shell activated carbon obtained by ordinary methods. About 60% higher, the two filtrates and washes are treated by anaerobic digestion, mixed with grass ash and wood ash, and used as organic fertilizer.

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Abstract

The invention relates to a method for preparing a carbon material at low temperature and co-producing a fertilizer. Processes of carbon source pyrolysis and carbon material activation are integrated; through a green process route in a closed system, low-temperature preparation of carbon is achieved; the produced carbon material can be further activated, modified and the like. By the method, the defects of high energy consumption, low yield, high dust pollution, a complicated posttreatment process, and serious environment pollution and difficult treatment of a waste solution and the like in the current carbon producing process are overcome; through the control of the types and the addition amounts of a carbon source and an activator as well as the temperature and the residence time in a reaction kettle, continuous clean production of the carbon material is achieved; through adjustment of the pH or the components, the produced waste solution is used as the fertilizer, so that harmless treatment and high-value conversion of the waste are achieved. In the method, the carbon source is wide (including biomass carbon, tar carbon, bitumen carbon and the like); by the method, the reaction condition is mild, the yield is high, the waste emission is avoided, the energy is saved and the consumption is lowered; therefore, the method is an environmentally friendly, efficient and economical method for sustainably producing the carbon material and co-producing the fertilizer.

Description

technical field [0001] The invention discloses a sustainable technology method for green, clean, and low-temperature preparation of carbon materials for co-production of fertilizers, and relates to a low-temperature preparation process of carbon materials and high-value resource utilization of reaction by-products. Background technique [0002] Carbon materials have the advantages of a wide variety, light weight, adjustable pore structure and specific surface area, chemical stability, and good catalytic activity. They are used in fuels, sewage treatment, soil remediation, catalysis, energy storage and conversion, fertilizers, coatings, etc. Widespread, the demand has continued to increase in recent years. Biomass materials are renewable organic resources with a large reserve on the earth, but a large part of them exists in the form of biomass waste, such as agricultural and forestry product waste, which has become an important source of environmental pollution. The petroche...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/318C01B32/324C01B32/33C01B32/342C01B32/348C01B32/336C05B7/00C05G1/00
CPCC05B7/00C05C3/00C05D1/00C05F7/00
Inventor 王贵欣邹江东许飞闫康平
Owner SICHUAN UNIV
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