Double-network reinforced composite quick-drying gel cement material and preparation method thereof

A technology for strengthening composite and cement materials, applied in the field of building materials, can solve the problems of consumption and maintenance costs, high maintenance costs, economic losses, etc., and achieve the effects of preventing brittle fracture, improving mechanical properties, and improving flexural strength and ductility.

Active Publication Date: 2019-12-31
新化县天马建筑新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some concrete structures such as roads, bridges and tunnels, ground and underground buildings, underground pipelines, and utility poles and towers in the western region were severely damaged due to sulfate erosion after only a few years of use, and large-scale restoration work had to be carried out, consuming Huge maintenance costs resulting in huge economic losses
It can be seen that the problem of sulfate corrosion of concrete is a very prominent problem in my country, not only because of the high maintenance costs of damaged concrete structures, but also because of the lack of cement materials that are resistant to corrosion, high in bending resistance and not easy to break from the source.
[0004] Chinese patent 201710897493.7 discloses an environmentally friendly decorative cement. The technical so

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A double-network reinforced composite quick-drying gel cement material provided in this embodiment comprises the following components by weight:

[0048] 30 parts of polyhydroxyethyl methacrylate;

[0049] 35 parts of polycarbon fiber-acrylamide-hydrated calcium silicate double network polymer;

[0050] 10 parts of wheat straw, 5 parts of sisal fiber;

[0051] 10 parts of bentonite nanoparticles;

[0052] 10 parts of surfactant;

[0053] 10 parts of graphene;

[0054] 10 parts of hexagonal boron nitride;

[0055] 2 parts boric acid;

[0056] 10 parts of tricalcium phosphate;

[0057] 5 parts of potassium persulfate / sodium sulfite redox system initiator;

[0058] 4 parts of sorbitol;

[0059] Polycarboxylate superplasticizer 3 parts.

[0060] Wherein the molar ratio of potassium persulfate to sodium sulfite is 1:5.

[0061] Among them, the carbon fiber-polyacrylamide-polyhydrated calcium silicate double network polymer is the first network structure of carbon f...

Embodiment 2

[0069] A double-network reinforced composite quick-drying gel cement material provided in this embodiment comprises the following components by weight:

[0070] 35 parts of polyhydroxyethyl methacrylate;

[0071] 42 parts of polylactic acid-hydrated sulfoaluminate double network polymer;

[0072] 18 parts of corn stalks;

[0073] 15 parts of bentonite nanoparticles;

[0074] 15 parts of surfactant;

[0075] 15 parts of graphene;

[0076] 15 parts of hexagonal boron nitride;

[0077] 3 parts of boric acid;

[0078] 7 parts of carbon fiber;

[0079] 12 parts of tricalcium phosphate;

[0080] 7 parts of ammonium persulfate / sodium dithionite redox system initiator;

[0081] 6 parts of galactitol;

[0082] Polycarboxylate superplasticizer 4 parts.

[0083] Wherein, the molar ratio of sodium dithionite to ammonium persulfate is 1:2.

[0084] Carbon fiber-polylactic acid-polyhydrated sulfoaluminate double network polymer is synthesized by the polymerization of carbon fiber...

Embodiment 3

[0092] A double-network reinforced composite quick-drying gel cement material provided in this embodiment comprises the following components by weight:

[0093] 40 parts of polyhydroxyethyl methacrylate;

[0094] Carbon fiber-polyacrylic acid-polyhydrated aluminosilicate double network polymer 48 parts;

[0095] 10 parts of palm fiber, 10 parts of sugarcane fiber;

[0096] 20 parts of bentonite nanoparticles;

[0097] 20 parts of surfactant;

[0098] 20 parts of graphene;

[0099] 20 parts of hexagonal boron nitride;

[0100] 5 parts of boric acid;

[0101] 15 parts of tricalcium phosphate;

[0102] 10 parts of potassium persulfate / sodium bisulfite redox system initiator;

[0103] 8 parts of D-mannitol;

[0104] Polycarboxylate superplasticizer 5 parts.

[0105] Wherein, the mol ratio of sodium bisulfite and potassium persulfate is 3:5.

[0106] Carbon fiber-polyacrylic acid-polyhydrated aluminosilicate double network polymer is an organic second network synthesized by...

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Abstract

The invention provides a dual-network reinforced composite quick-drying gel cement material and a preparation method thereof. The material comprises the following components in parts by weight: 30-40parts of polyhydroxyethyl methacrylate; 35-48 parts of a carbon fiber-organic-inorganic double-network polymer; 15-20 parts of plant fiber; 10-20 parts of bentonite nanoparticles; 10-20 parts of a surfactant; 10-20 parts of graphene; 10-20 parts of hexagonal boron nitride; 2-5 parts of boric acid; 10-15 parts of tricalcium phosphate; 5-10 parts of a redox system initiator; 4-8 parts of a crosslinking agent; and 3-5 parts of a polycarboxylate superplasticizer. The carbon fiber-organic-inorganic double-network polymer produced by using industrial production waste is adapted to graft the plant fiber, and a good graft copolymerization effect with polyhydroxyethyl methacrylate is achieved, the flexural strength and ductility of the synthesized cement material are enhanced, and addition of graphene can make a cement system form a self-monitoring system that monitors various parameters of concrete.

Description

technical field [0001] The invention relates to cement, which belongs to the technical field of building materials, in particular to a dual-network reinforced composite quick-drying gel cement material and a preparation method thereof. Background technique [0002] Cement concrete is one of the building materials widely used in the world today. However, some non-mechanical failures often occur in cement concrete structures before reaching the designed service life. Sulfate attack damage is one of the common non-mechanical damage forms of concrete. my country has a vast ocean area and a long coastline. The concentration of sulfate ions in seawater is about 2.54-3.06g / L, while the salt content in coastal saline soil is generally higher than 5%. Therefore, the cement concrete structure in the marine environment is During service, it will inevitably be corroded by sulfate in seawater[. For example, some marine projects, sea-crossing bridges, offshore oil production platforms, s...

Claims

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Application Information

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IPC IPC(8): C04B28/18C08L33/26C08L67/04C08L33/02C08K7/06C08K3/34C08K3/30
CPCC04B28/188C08K3/30C08K3/34C08K7/06C04B14/386C04B24/2652C04B24/02C04B22/147C04B18/248C04B14/024C04B2103/40C04B22/16C04B24/2641C04B14/104C04B14/327C04B22/0013C04B24/24C08L33/26C08L33/02C08L67/04
Inventor 陈克坚
Owner 新化县天马建筑新材料科技有限公司
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