Functional material capable of visually degrading formaldehyde and VOCs (Volatile Organic Compounds) at normal temperature and normal pressure and preparation method thereof

A functional material, normal pressure technology, applied in the fields of big health, environmental protection, new materials and gas pollution control, gas purification, can solve problems such as physical health hazards, limited wide application, easy damage, etc., to meet the requirements of low use environment, use Expansive, highly reactive effects

Active Publication Date: 2021-07-23
NANJING MASTER HEALTH TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Noble metal catalysts cannot be widely used due to the high cost of noble metals and their susceptibility to temperature and pollution
Chinese patent CN10380574 discloses a catalyst for catalytic oxidation of formaldehyde at room temperature. The catalyst component is 0.2-30% according to the metal loading, preferably 1-10%. The cost is too high and it is not easy to popularize
Chinese patent CN1698932A uses Au as a noble metal to catalyze the oxidation of formaldehyde, but only at a higher temperature (80-100°C) can it exert better catalytic efficiency, which limits its wide application
However, since potassium permanganate itself is a strong oxidizing substance, it is easy to damage the surface of furniture or clothing in contact with it alone. In addition, the color change range of this material is from red to brown, and the color change is not sensitive.
Chinese patent CN 102527228 A discloses a visually discolored formaldehyde scavenger, which is composed of three components: an adsorption component, a catalytic component and a discoloration component, although it can discolor after contacting formaldehyde, etc. The discoloration is dependent on the effect of the acid-base indicator, rather than the discoloration caused by the failure of the active functional components in the true sense, and it cannot directly indicate the change of the purification ability of the material
[0009]Furthermore, most of the existing technologies have only studied the catalytic oxidation effect of catalysts on formaldehyde, but in fact, in indoor and car interior spaces, it is harmful to human health. More serious is benzene and its homologues
On the other hand, since benzene and its homologues are also important components that cause indoor and car odors, those catalysts or reactions that can only catalyze the oxidation of formaldehyde cannot really reduce indoor, car, and space odors

Method used

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  • Functional material capable of visually degrading formaldehyde and VOCs (Volatile Organic Compounds) at normal temperature and normal pressure and preparation method thereof
  • Functional material capable of visually degrading formaldehyde and VOCs (Volatile Organic Compounds) at normal temperature and normal pressure and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] Preparation of Example Material 1: Weigh 23.5g of white carbon black, 17.2g of titanium dioxide, and 46.5g of activated carbon, mix and stir evenly, and heat in a muffle furnace at 850°C for 12h to form a loading agent. In the hydrochloric acid ethanol solution containing 13.1g nickel sulfate, 2.1g nitric acid, 4g cobalt nitrate, add 1.5g aluminum potassium sulfate, 1.1g sodium sulfate, adjust pH and temperature with 0.2~2mol / L ammonia water, make just have Precipitate, then add loading agent, adjust pH with 0.1-3 mol / L citric acid, place in 95°C water bath and stir for 24 hours to slowly form precipitate, stand for aging, and separate solid. The solid is calcined in a muffle furnace at 1000°C for 10 hours in a nitrogen atmosphere to obtain a functional material for visually degrading formaldehyde and VOCs at normal temperature and pressure. The prepared material will change from black to yellow-brown after reacting with formaldehyde and VOCs at normal temperature and p...

Embodiment 2

[0068] Weigh 21.8g of perlite, 19.6g of calcium carbonate, and 15.8g of kaolin, mix and stir evenly, and heat in a muffle furnace at 900°C for 15h to form a loading agent. In the sulfuric acid ethanol solution containing 16.2g ferric chloride, 15.8g potassium dichromate, 16.2g cobalt sulfate, add 0.11g sodium tartrate, 2.5g sodium borate, adjust pH and The temperature is such that there is just precipitation in the solution, and then the loading agent is added, the pH is adjusted with 0.1-0.5 mol / L hydrochloric acid, placed in a water bath at 80°C and stirred for 12 hours, left to age, and the solid is separated. The solid is calcined in a muffle furnace at 800°C for 12 hours in a nitrogen atmosphere to obtain a functional material for visually degrading formaldehyde and VOCs at normal temperature and pressure. The prepared material will change from purple to black after reacting with formaldehyde and VOCs at normal temperature and pressure, and the removal efficiency of forma...

Embodiment 3

[0070] Weigh 5.9g of diatomaceous earth, 4.6g of zeolite, 3.1g of gypsum, and 35g of barium sulfate, mix and stir evenly, and heat in a muffle furnace at 1000°C for 24h to form a loading agent. In the hydrochloric acid aqueous solution containing 15.7g iron sulfate, 0.09g potassium permanganate, 2.3g zinc nitrate, add 5.3g sodium pyrophosphate, 18g potassium phosphate, adjust pH and temperature with 0.2~2mol / L sodium bicarbonate solution, Just make the solution precipitate out, then add the loading agent, adjust the pH with 0.1-2mol / L acetic acid, put it in a 95°C water bath and stir for 24h, let it stand for aging, and separate the solid. The solid is calcined in a muffle furnace at 1000°C for 10 hours in a nitrogen atmosphere to obtain a functional material for visually degrading formaldehyde and VOCs at normal temperature and pressure. The prepared material will change from purple red to earthy yellow after reacting with formaldehyde and VOCs at normal temperature and press...

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Abstract

The invention provides a functional material for visually degrading formaldehyde and VOCs (Volatile Organic Compounds) at normal temperature and normal pressure. The functional material comprises a loading agent, an oxidizing agent, a catalyst, a reinforcing agent and a ligand. The reaction efficiency is improved through the synergistic strengthening effect of the loading agent, the oxidizing agent, the catalyst, the reinforcing agent and the ligand, so that the material has an excellent effect of degrading formaldehyde and VOCs at normal temperature and normal pressure, the structure and color of the material are changed before and after the reaction with formaldehyde and VOCs, and the reaction speed and degree can be directly observed and indicated by naked eyes. The material prepared by the invention not only can degrade formaldehyde, but also can degrade various VOCs (Volatile Organic Compounds). Due to the synergistic strengthening effect, all the components are evenly distributed, firmly combined and resistant to water and moisture, the material can be made into a solid state or a liquid state, and the problems of performance degradation, structural damage and the like after a solid catalyst absorbs water are essentially solved. The functional material is used in the fields of environmental protection and health, and is especially important for treatment of pollution gas and industrial VOCs in space.

Description

technical field [0001] The invention belongs to the field of new materials and gas pollution control, and specifically relates to a functional material and a preparation method for visually degrading formaldehyde and VOCs at normal temperature and pressure, which are used in the fields of gas purification, environmental protection, and general health. Background technique [0002] With the continuous development of the economy and the rapid development of real estate, automobile, chemical, pharmaceutical, textile and other industries, people's requirements for housing, travel, clothing, medical care, living environment, etc. are constantly increasing. However, the existing production methods of material materials are accompanied by a large amount of polluting gas emissions. On the one hand, various decoration materials in the interior, car, and space, such as formaldehyde and VOCs (volatile organic compounds); on the other hand, a large number of industrial enterprises emit ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/86B01D53/72B01D53/44F24F8/167B01J23/755
CPCB01D53/8668B01D53/8687F24F3/16B01J23/755B01D2257/708Y02A50/20
Inventor 王丹亮万远鑫韩小兵
Owner NANJING MASTER HEALTH TECH CO LTD
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