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Innocent treatment of alcohol slops and application technique

A technology of harmless treatment and application technology, applied in water/sewage multi-stage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve the problems of high viscosity, low added value and high chromaticity

Inactive Publication Date: 2014-02-05
GUANGXI NEW ORIENTATION CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The molasses alcohol waste liquid has the following characteristics: the CODcr value of the waste water is 8~50×10 4 mg / L, BOD5 value is 4~6×10 4 mg / L, good biodegradability, high-concentration organic wastewater; solid content up to 10% to 20%, capable of drying and recycling, but high viscosity and low added value; contains a lot of organic matter, protein, vitamins, N, P, K, etc. , non-toxic and harmless; pH value 5-6.5, containing inorganic acid and organic acid, strong corrosiveness; high chroma, containing melanoid, difficult to remove physically and chemically
These industrial waste liquids cannot be discharged directly without treatment, otherwise they will seriously affect the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] The invention provides a harmless treatment using industrial alcohol waste liquid: waste liquid acidification: 60 parts of waste liquid, adding 1 part each of nitric acid, iodine water, citric acid, gallic acid, and tannic acid; oxidation treatment: acidifying waste liquid , adding 2 parts of potassium perchlorate, m-chloroperoxybenzoic acid, 2-iodylbenzoic acid, and hydrogen peroxide for oxidation reaction; biochemical treatment: waste liquid after oxidation, adding 0.1 part of Bacillus subtilis, antifungal bacteria, EM bacteria, 0.1 parts of lactic acid bacteria for biochemical reaction; neutralization treatment: waste liquid after biochemical treatment, add 3 parts of potassium hydroxide, 0.5 parts of magnesium hydroxide, 0.5 part of calcium oxide; flocculation treatment: after neutralization of waste liquid, add PAM, 0.1 parts each of chitosan, ferric sulfate, lignosulfonate, and methacrylic acid; finally stand still for 10 days, separate and precipitate, and obtain ...

Embodiment 2

[0013] The invention provides a harmless treatment using industrial alcohol waste liquid: waste liquid acidification: 60 parts of waste liquid, add nitric acid, hydrochloric acid, iodine water, oxalic acid, citric acid, gallic acid, each add 2.5 parts; oxidation treatment, take Acidify waste liquid, add potassium permanganate, m-chloroperoxybenzoic acid, 2-iodyl benzoic acid, manganese dioxide, hydrogen peroxide 1.5 parts each; Bacillus thuringiensis, Bacillus thuringiensis, lactic acid bacteria, Brevibacterium thiogenus each 0.1 parts; neutralization treatment: waste liquid after biochemical treatment, add sodium hydroxide, calcium hydroxide, potassium hydroxide, magnesium oxide, 2.5 parts each. Flocculation treatment: Add PAM, aluminum chloride, ferric chloride, lignin sulfonate, and acrylic acid to the waste liquid after neutralization, each adding 0.2 parts; finally carry out precipitation for 15 days, and separate treatment to obtain mother liquor.

Embodiment 3

[0015] The invention provides a harmless treatment using industrial alcohol waste liquid: waste liquid acidification: 70 parts of waste liquid, add 2 parts each of nitric acid, perchloric acid, sulfuric acid, citric acid, and gallic acid; oxidation treatment: take acidified waste Liquid, add potassium permanganate, m-chloroperoxybenzoic acid, 2-iodylbenzoic acid, manganese dioxide, sodium dioxide, hydrogen peroxide, add 1 part each to carry out oxidation reaction. Biochemical treatment: take the waste liquid after oxidation, add Bacillus subtilis, antimycobacterium, colloidal bacillus, brevibacterium flavum, each addition amount is 0.1 parts to carry out biochemical reaction; neutralization treatment: waste liquid after biochemical treatment, add sodium hydroxide, Add 1.5 parts each of potassium hydroxide, calcium oxide, and magnesium oxide. Flocculation treatment: 70 to 90 parts of waste liquid after biochemical treatment, add aluminum sulfate, chitosan, ferric chloride, lign...

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PUM

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Abstract

The invention relates to treatment of industrial wastes and a use of the industrial waste in producing an organic liquid fertilizer, and is applied to the fields of agriculture and forestry. Industrial liquid wastes include an alcohol liquid waste, a molasses liquid waste and a starch fermentation liquid waste; the industrial liquid wastes contain lots of nutrient elements needed by plants, such as amido acids, humic acids and organic matters, and also contain some harmful bacteria; water insoluble matters, suspended matters and the COD (Chemical Oxygen Demand) value in the industrial liquid wastes are about 5*10<5>mg / L; therefore, if the industrial liquid wastes are directly used without treatment, hazards such as environmental pollution and rot roting and seedling wilting of plants can be caused. Innocent treatment of liquid wastes mainly comprises the following steps of acidification, oxidization, biochemical treatment, neutralization, flocculation and precipitation separation treatment; after the industrial liquid wastes are subjected to innocent treatment, the mother liquor obtained is used for producing a green environment-friendly organic liquid fertilizer; the fertilizer is capable of achieving the effects of promoting crops to absorb nutrients, keeping nutrient balance and improving the taste and quality of products, and the yield of crops can be increased by 20-40%; therefore, the fertilizer is an organic green environment-friendly liquid fertilizer.

Description

technical field [0001] The invention relates to the treatment and application technology of industrial alcohol waste liquid, molasses waste liquid and starch fermentation waste liquid. Background technique [0002] Molasses alcohol waste liquid refers to the waste water discharged after the fermented mash is distilled out of alcohol in the alcohol primary distillation tower after fermentation with molasses as raw material. About 15-20 tons of waste water is discharged for every 1 ton of alcohol produced. At present, my country discharges more than 6 million tons of such waste water annually. The molasses alcohol waste liquid has the following characteristics: the CODcr value of the waste water is 8~50×10 4 mg / L, BOD5 value is 4~6×10 4 mg / L, good biodegradability, high-concentration organic wastewater; solid content up to 10% to 20%, capable of drying and recycling, but high viscosity and low added value; contains a lot of organic matter, protein, vitamins, N, P, K, etc. ,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14
Inventor 陈成吴宁芮长情
Owner GUANGXI NEW ORIENTATION CHEM IND
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