Heavy metal wastewater treatment technology, processing method thereof, and medicine production formula

A technology for wastewater treatment and heavy metals, applied in water/sewage treatment, sustainable waste treatment, multi-stage water/sewage treatment, etc.

Inactive Publication Date: 2014-02-19
叶绍朋
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims at the above-mentioned heavy metal wastewater pollution treatment problem, and provides a heavy metal wastewater treatment method and a production process of heavy metal wastewater treatment agent Y3-8013. After the heavy metal-containing wastewater is treated with Y3-8013, the heavy metal content in the effluent is not more than 0.0001mg / l- 0.00001mg / l, cadmium≤0.0001mg / l-0.00001mg / l, mercury≤0.001mg / l-0.00001mg / l, arsenic≤0.0001mg / l-0.00001mg / l, nickel≤0.0001mg / l-0.00001mg / l, copper≤0.0001mg / l-0.00001mg / l, silver≤0.0001mg / l-0.00001mg / l, gold≤0.0001mg / l-0.00001mg / l, cobalt 60≤0.0001mg / l-0.00001mg / l l, thallium≤0.0001mg / l-0.00001mg / l, uranium≤0.0001mg / l-0.00001mg / l, plutonium≤0.0001mg / l-0.00001mg / l, manganese≤0.0001mg / l-0.00001mg / l, Chromium≤0.01mg / l-0.001mg / l, CODcr≤30mg / l-50mg / l, pH=6-9, NH3-N≤1.0mg / l, TP≤0.1mg / l, meet the "urban domestic sewage treatment The Class A discharge standard in the Factory Pollutant Discharge Standard (GB18918-2002) can be directly discharged to rivers, lakes, oceans or reused by enterprises

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The technical process of heavy metal wastewater treatment includes the following steps:

[0029] (1) Prepare and mix the following components by weight into a special treatment agent (Y3-8013)

[0030] 2%-3% marble, 5%-6% talc, 5%-6% reduced iron powder, 18%-19% lapis lazuli, 1%-2% mullite, 3%-4 % serpentine, 20%-21% pyrite, 0.3%-0.4% kaolin, 0.4%-0.5% attapulgite, 2%-3% bauxite, 5%-6% diatomite, 4%-5% rhodochrosite, 0.3%-0.5% montmorillonite, 5%-5.4% granite, 1%-2% bentonite, 3%-3.1% yuan Mingfen, 25%-13.1% 5000kj / kg-6000kj / kg natural coal bituminous coal or anthracite.

[0031] ·In an electric furnace below 580℃-1100℃, under the protection of helium gas, red-hot calcining the mixed ore for 6-12 hours, and naturally cool to room temperature in the air. Pulverize to 60 mesh to 800 mesh, burn coal to calcine the volatilized part, and supplement the remaining weight with talc and attapulgite to make 100%.

[0032]·Prepare 8%-12% 98% citric acid, 7%-13% 98% glacial ace...

Embodiment 2

[0040] 【2】Alkaline wastewater treatment process with heavy metals

[0041] Using formula (1), 3.1% marble, 2.3% talc, 22% lapis lazuli, 1.5% mullite, 0.9% serpentine, 20% pyrite, 0.9% kaolin, 1 % attapulgite, 1% bauxite, 3% diatomite, 1% rhodochrosite, 0.6% montmorillonite, 1.5% granite, 0.8% bentonite, 35% yuan Ming powder and thermal coal with the remaining amount of 5000kj / kg are red-hot calcined for 6 hours in an electric furnace below 1000 ℃ under the protection of helium gas, and cooled to room temperature naturally in the air. Pulverize to 800 mesh, burn the coal calcined volatilized part, use 600 mesh talc, kaolin, diatomite, attapulgite = 1:1:1 to supplement the remaining weight reduced by burning coal volatilization and ore calcination to 100 %. A heavy metal wastewater treatment agent is obtained.

[0042] Prepare a mixture of 8% citric acid, 6% glacial acetic acid, 10% 1:1 nitrous acid + 3% nitrogen dioxide saturated solution 30% + nitric acid 50%, 15% phosphori...

Embodiment 3

[0047] In the heavy metal wastewater containing radioactive uranium U238 and 235, thorium containing thallium, lead, cobalt-60, Sr-90, thallium Tl, first use 10,5% 1:1 content of 30% nitrous acid and dioxide Mix acid with saturated solution of nitrogen dissolved in water, adjust the pH value of wastewater to 0.1, add treatment agent Y3-8013 and mix and stir for 5 to 10 minutes. The content of radioactive heavy metals uranium U238 and 235, thorium containing thallium, lead, cobalt-60, strontium-90, and thallium Tl in the effluent is less than or equal to 0.00000001mg / l, the content of radioactive elements in the effluent reaches the standard discharge, and the sediment contains all Radioactive elements can be recovered by adsorption and solidification of ionized grafted polysilicate, and finally transformed into stable elements with lead fixation after half-life.

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PUM

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Abstract

The invention relates to a heavy metal wastewater treatment technology, a processing method thereof, and a medicine production formula. A certain proportion of an aqueous solution of a mixed acid is added to wastewater containing heavy metals and radioactive heavy metals, a special medicine for the heavy metal wastewater treatment is added, the obtained mixed solution undergoes a mixing and stirring reaction for precipitation, and the pH value of discharged water is controlled in a range of 6-9 through the quantity of the medicine addition amount in order to realize the copolymerization coagulation precipitation of reacted heavy metal compounds. The content of each of Pb, Cd, Hg, As, and radioactive elements comprising Co-60, Tl, Sr-90, Pu, Th and U235 is not greater than 0.0001-0.00001mg / l, and the CODcr is not greater than 20-50mg / l, so discharged water can be discharged to urban domestic sewage treatment plants or rivers, lakes and seas. Waste residues containing a non-overload amount of the radioactive elements can be processed to form non-fired termiticide bricks added with a color sign, the treatment cost is low, and the treatment problem of the worldwide heavy metal pollution and the radioactive heavy metal pollution of water is solved.

Description

technical field [0001] The invention relates to the field of heavy metal waste water treatment, the field of comprehensive utilization of heavy metal waste residue treatment, the technical process of heavy metal waste water treatment and the production process of treatment chemicals (the applicant is compiled as: Y3-8013 special medicine for heavy metal waste water treatment). Lead, cadmium, mercury, chromium, nickel, copper, manganese, tin, silver, gold, thallium, uranium, thorium, cobalt-60, strontium-90, plutonium non-metallic arsenic and other industrial wastewater containing dozens of heavy metal pollution, treatment Heavy metal pollution in rivers, lakes and oceans. Background technique [0002] For a long time, in developing countries and even developed countries, urban waste, lead-acid battery manufacturing, heavy metal mining, radioactive heavy metal mining and processing, nuclear pollution wastewater discharge, heavy metal smelting, thermal power generation, electr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F1/62G21F9/06C04B28/00A01N59/22A01P7/04C04B18/30
CPCY02W30/91
Inventor 叶绍朋
Owner 叶绍朋
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