The invention discloses alloy for a precise machining clamp and a preparation method for the alloy. The clamp comprises the following raw materials of, by mass, 1.5%-2.3% of beryllium powder, 1.9%-2.7% of zirconium powder, 5.3%-6.1% of calcium, 3.0%-3.8% of molybdenum powder, 0.8%-1.5% of vanadium powder, 0.3%-0.7% of tin powder, 7.2%-8% of copper powder, and the balance aluminum powder. According to the alloy for the precise machining clamp and the preparation method for the alloy, the alloy obtained after the beryllium powder, zirconium powder, calcium, molybdenum powder, vanadium powder, tin powder, copper powder and aluminum powder are subjected to smelting, rapid hardening, hydrogen decrepitation, cold press molding and segmental calcination under the action of scientific cooperation of the component contents is uniform in structure, has high hardness, high breaking tenacity and corrosion resistance, can be applied to the precise machining clamp, and can further eliminate residual stress of a high-temperature part when being matched with the high-temperature part, and the usage reliability and the size precision of the part are ensured. The alloy for the precise machining clamp and the preparation method for the alloy have the advantages that service life is long, high production efficiency is high, the size precision of the machined part is high, the part product quality and yield are improved, pollution to the environment is avoided, and the alloy and the preparation method are suitable for industrial production.