The application relates to the technical field of organic photoelectric materials, and particularly discloses an
aryl-trisubstituted
benzanthracene organic electroluminescent compound and a double-emitting-layer organic electroluminescent device thereof. The structural general formula of the
aryl-trisubstituted
benzanthracene organic electroluminescent compound is shown as formula I, Ar1 and Ar3 each independently represent any one or a combination of any two of deuterated or non-deuterated
aryl with 6-30 carbon atoms, deuterated or non-deuterated condensed ring aryl with 10-30 carbon atoms; Ar2 represents deuterated or non-deuterated phenyl or naphthyl; any
hydrogen in formula I can be independently substituted by
deuterium. By introducing the
substituent defined in the application to the 4th, 7th and 12th positions of
benzanthracene, the
thermal stability of the compound can be improved, the molecular orientation can be improved, the PL spectrum peak of the compound provided by the application can be well overlapped with the absorption spectrum of a BD material, and energy transmission is more favorable.