The invention relates to a hydrated borate micromolecule with a
boron-
nitrogen coordination bond, a derivative resin material and a preparation method of the hydrated borate micromolecule. The preparation method comprises the following steps: S1, synthesizing
boron-
nitrogen coordination micromolecules: dissolving and reacting
boric acid, a derivative thereof and a polyfunctional group amine compound at
room temperature through a solution reaction to obtain the
boron-
nitrogen coordination micromolecules; the borate micromolecule NCBW-X with intramolecular boron and nitrogen coordination is formed; s2, the NCBW-X micromolecule can be used for curing
epoxy resin and synthesizing materials such as phenolic resin through end-NH2 and end-OH on two sides, the NCBW-X improves the
mechanical property of each
system through a rigid eight-membered ring, boron-nitrogen coordination of the NCBW-X can generate hydration, the environmental endurance is improved on the premise of retaining the original dynamic nature of
boric acid ester of the NCBW-X, and the service life of the NCBW-X micromolecule is prolonged. Meanwhile, due to the dynamic reversibility of the NCBW-X, the NCBW-X is used for curing
epoxy resin, and materials such as phenolic resin and the like are improved to a certain extent in the aspects of self-repairing and recycling.