The invention particularly discloses a moon roof type air purifier device for a passenger car and a working method of the moon roof type air purifier device. The device comprises a flow guide air flue base, a ventilation opening, a flow guide plate, air walls, fixing plates, filtering net inserting grooves, L-shaped filtering net fixing grooves, fixed supporting bases, a cover plate, a partition board, fixing pieces, plasma assemblies, ultraviolet lamps and fans. The device has the following advantages that the size of a purification bin is increased, and the moon roof type air purifier device is short in purifying time when being used for purifying a passenger car with the same carriage area; one-time assembly of the plasma assemblies, the fans, the ultraviolet lamps and filtering nets can be achieved, and production efficiency is improved by 300%; the purification bin is reasonable in design, the utilization rate of materials is improved, and cost and investment are reduced; by means of the fans which are independently arranged in different spaces, the situation that air power is reduced due to parallel connection of the fans during normal work of the device does not exist; according to test detection, processing efficiency of the device for formaldehyde, toluene, dimethylbenzene and TVOC reaches 95% per hour, the processing efficiency for PM2.5 reaches 98% per hour.