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High-temperature-resistant bending-resistant ethylene propylene rubber insulated cable for rail transit, preparation method thereof and insulating material

An ethylene-propylene rubber insulation and rail transit technology, applied in the field of cables and cable materials, can solve problems such as low pressure and temperature resistance, slow vulcanization speed, and complicated process flow

Pending Publication Date: 2020-06-30
江苏中超电缆股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

EPDM rubber is a polymer composed of propylene, ethylene and conjugated diene. Since the carbon atoms on the main chain are in a saturated structure, and only a few unsaturated carbon atoms are on the side chains, it has many excellent processing properties. Performance and use performance, such as low density, weather resistance, heat resistance and ozone resistance, excellent mechanical properties, etc.; but EPDM rubber also has disadvantages such as oil resistance, poor adhesion, and slow vulcanization speed
[0012] However, in the above-mentioned various methods, the peroxide chemical cross-linking method to prepare EPDM cables has the disadvantages of low production efficiency and complicated process flow, and it needs to be carried out for a long time through tens of meters of high-pressure and high-temperature steam vulcanization pipelines. Time cross-linking consumes a lot of energy, and the utilization rate of energy efficiency is very low. The effective utilization rate of heat energy is only about 10%, and it has high requirements for plant design and manufacturing equipment, and the investment is relatively large, especially for manufacturing. The technical level of personnel is extremely high. Since the sulfur pipeline is closed when starting up, the appearance of the cable cannot be observed intuitively, so the product quality is difficult to control, the yield rate is low, the manufacturing waste is great, and the production of small cross-section cables is even more difficult. It is even more difficult, and the temperature resistance level can only reach 90°C, which is not conducive to the production of ethylene-propylene rubber insulated rail transit vehicle cables; the equipment investment of the high-energy radiation cross-linking method is relatively high, the operation and maintenance are more complicated and the protection conditions are harsh, and due to Its process characteristics are only suitable for making wires with smaller wire diameters and not for cables with larger wire diameters; while the silane crosslinking method involves hydrolysis reactions, the stability of the products is poor, and the pressure and temperature resistance grades are also low.

Method used

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  • High-temperature-resistant bending-resistant ethylene propylene rubber insulated cable for rail transit, preparation method thereof and insulating material
  • High-temperature-resistant bending-resistant ethylene propylene rubber insulated cable for rail transit, preparation method thereof and insulating material
  • High-temperature-resistant bending-resistant ethylene propylene rubber insulated cable for rail transit, preparation method thereof and insulating material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073] Such as figure 1 The shown high temperature and bending resistant ethylene-propylene rubber insulated cable for rail transit includes conductor 1, which uses six types of annealed copper conductors, is resistant to bending, and has a large bending radius; the conductor is wrapped with a first polyetheretherketone The film wrapping layer 2 and the second polyether ether ketone film wrapping layer 4 make the cable have excellent mechanical properties, electrical properties, high temperature resistance (the mechanical strength does not decrease at a high temperature of 240°C), and good flame retardancy: no need High flame retardancy, excellent electrical insulation properties due to the use of flame retardant additives: high dielectric strength, stable dielectric properties at various temperatures, frequencies and temperatures, radiation resistance, hydrolysis resistance and a wide range of chemical resistance : Insoluble in all common solvents—excellent acid, alkali, lubr...

Embodiment 2

[0075] A method for preparing an ethylene-propylene rubber insulated cable for high-temperature and bending-resistant rail transit, comprising the following steps:

[0076] 1) Preparation of conductor:

[0077] 1-1) Wire drawing: first draw a copper rod with a diameter of 3mm on a LT2-15 / 350 copper wire drawing machine into a copper wire with a diameter of 0.99mm, and the dimensions of the drawing dies are: 2.76, 2.55, 2.35, 2.16, 1.99, 1.83, 1.69, 1.56, 1.43, 1.32, 1.02mm; the copper wire outlet speed is 10-20m / s, the maximum annealing current is 1200A; Small drawing machine wires are drawn into copper wires with a diameter of 0.3-0.5 mm. The size of the wire drawing dies can be: 0.83, 0.74, 0.65, 0.59, 0.52, 0.46, 0.40, 0.35, 0.31 mm, and the copper wires appear at a speed of 8~16m / s, the maximum annealing current is 600A;

[0078] 1-2) Bundling: 23 to 63 copper wire bundles with a diameter of 0.3 to 0.5 mm are formed into strands through a DF-GJ / 500 wire bundle machine, a...

Embodiment 3

[0097] A 150°C low-smoke halogen-free flame-retardant modified irradiated ethylene-propylene rubber insulating material, including the following components in parts by mass:

[0098] EPDM rubber: 45 parts, superfine polyimide resin powder: 18 parts, dioctyl phthalate: 5 parts, graphene: 1 part, white oil: 3 parts, maleic anhydride: 1 part , trimethylolpropane trimethacrylate: 1 part, magnesium hydroxide inorganic flame retardant: 5 parts, RCA aluminate coupling agent: 0.1 part, antioxidant and anti-copper agent 1024: 0.3 part, stearic acid Zinc: 0.5 parts.

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Abstract

The invention discloses a high-temperature-resistant bending-resistant ethylene propylene rubber insulated cable for rail transit and a preparation method thereof. The cable comprises a conductor, anda first polyether-ether-ketone film wrapping layer and a second polyether-ether-ketone film wrapping layer are sequentially wrapped outside the conductor. A 150 DEG C low-smoke halogen-free flame-retardant modified irradiation ethylene propylene rubber insulating layer is extruded outside the first polyether-ether-ketone film wrapping layer and the second polyether-ether-ketone film wrapping layer; a Twaron aramid fiber yarn woven reinforcing layer is woven outside the second polyether-ether-ketone film wrapping layer, and then the second polyether-ether-ketone film wrapping layer is wrappedwith a polyimide film wrapping layer; an outer surface of the polyimide film wrapping layer is coated with a ZS-322 transparent high-temperature-resistant heat-insulating coating, a high-temperature-resistant heat-insulating coating layer is formed after drying, and a high-toughness heat-resistant wear-resistant polyvinylidene fluoride outer sheath is extruded outside the high-temperature-resistant heat-insulating coating layer. The cable has excellent mechanical property, electrical property, high temperature resistance and good flame retardant property.

Description

technical field [0001] The invention relates to the field of cables and cable materials, in particular to an ethylene-propylene rubber insulated cable for high-temperature and bending-resistant rail transit, a preparation method for the cable, and an insulating material. Background technique [0002] The 21st century is a period of rapid development of my country's urban rail transit (including subways, ground light rails, and elevated light rails). Compared with other means of transportation, subways have the advantages of fast driving speed, large passenger transport volume, no floor space occupation, environmental protection and no exhaust emissions, etc. It is an effective way to solve the current urban traffic congestion and air pollution caused by exhaust emissions. With the rapid development of cities, the increasingly complex functions and the sharp increase in population, it is urgent to build a fast underground rail transit network. As an important supporting produ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B3/28H01B7/02H01B7/04H01B7/17H01B7/18H01B7/28H01B7/282H01B7/29H01B7/295H01B7/36H01B13/00H01B13/02H01B13/06H01B13/14H01B13/16H01B13/22H01B13/24H01B13/26H01B13/30
CPCH01B3/28H01B7/02H01B7/04H01B7/17H01B7/18H01B7/28H01B7/2806H01B7/282H01B7/29H01B7/295H01B7/365H01B13/00H01B13/02H01B13/06H01B13/14H01B13/165H01B13/22H01B13/24H01B13/2606H01B13/30Y02A30/14
Inventor 吴晓晨俞雷霍振平史明鹏吴林锴李志远
Owner 江苏中超电缆股份有限公司
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