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Co-extrusion film, solar cell module and double-layer glass

An adhesive film layer and adhesive film technology, applied in the direction of electrical components, glass/slag layered products, circuits, etc., can solve the problems of easy delamination of co-extruded adhesive films, long cross-linking time affecting the preparation cycle, etc., to reduce delamination Layer risk, facilitate industrialization, improve the effect of viscosity performance

Active Publication Date: 2022-04-15
HANGZHOU FIRST APPLIED MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The main purpose of the present invention is to provide a co-extruded adhesive film, solar cell module and double-layer glass to solve the problems that the co-extruded adhesive film produced by the existing technology is easy to delaminate, and the long cross-linking time affects the production cycle

Method used

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  • Co-extrusion film, solar cell module and double-layer glass
  • Co-extrusion film, solar cell module and double-layer glass

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] The raw material of the first adhesive film layer: by weight, get 30 parts of base resin ethylene-vinyl acetate copolymers (VA content is 28wt%, U.S. Dupont), 70 parts of vinyltrimethoxysilane grafted ethylene-acetic acid Vinyl ester copolymer (VA content is 28wt%, graft rate 2wt%, U.S. DuPont), add 1.5 parts of catalyst N, N-dimethylbenzylamine, 0.8 parts of crosslinking agent 2,5-dimethyl-2, 5-bis(tert-butylperoxy)hexane, 0.8 parts of trimethylolpropane trimethacrylate as a co-crosslinking agent.

[0049] The raw material of the second adhesive film layer: in parts by weight, get 10 parts of base resin ethylene-hexene copolymers (U.S. Dow), 80 parts of vinyltrimethoxysilane grafted ethylene-hexene copolymers (grafting rate 2wt%, American Dow), 10 parts of water producing agent calcium disulfate monohydrate masterbatch, 10 parts of water producing agent 1,3-propanediol. Among them, the calcium sulfate monohydrate master batch is obtained by granulating calcium sulfate...

Embodiment 2

[0052] The raw material of the first adhesive film layer: in parts by weight, get 100 parts of ethylene-octene copolymers grafted by isocyanate groups (grafting rate 3wt%, U.S. Dow), 1 part of catalyst ethylene glycol, 0.01 part of catalyst Stannous octoate, 2 parts crosslinker 1,1-bis(tert-amylperoxy)cyclohexane, 0.02 part crosslinker trimethylolpropane triacrylate, 1.0 part crosslinker ethoxylated triglyceride 0.8 parts of acrylate tackifier vinyl triperoxy tert-butyl silane, 0.8 parts of light stabilizer bis-2,2,6,6-tetramethylpiperidinol sebacic acid, 20 parts of titanium dioxide.

[0053] The raw material of the second adhesive film layer: in parts by weight, get 100 parts of ethylene-octene copolymers (grafting rate 3wt%, U.S. Dow) of isocyanate group grafting, 5 parts of water producing agents (calcium oxide and lauryl acid masterbatch), 20 parts of water generating agent 1,4-butanediol. Among them, the masterbatch of calcium oxide and lauric acid is obtained by granul...

Embodiment 3

[0056] The raw material of the first adhesive film layer: in parts by weight, 50 parts of base resin ethylene-propylene copolymers (U.S. Dow), 50 parts of ethylene-propylene copolymers (U.S. Dow) containing 1.0% acid anhydride, 2.5 parts of catalyst Sanya Ethylenediamine, 0.5 parts of cross-linking agent tert-butyl peroxyisopropyl carbonate, 0.9 parts of auxiliary cross-linking agent triallyl isocyanurate, 0.5 parts of tackifier vinyl triethoxysilane, 0.02 Parts light stabilizer bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate.

[0057] The raw material of the second film layer: in parts by weight, get 20 parts of ethylene-propylene copolymers (U.S. Dow) containing 1.0% acid anhydride, 80 parts of ethylene-pentene copolymers (U.S. Dow) containing 1.2% mercapto , 0.5 parts of catalyst N,N-dimethylcyclohexylamine, 2 parts of first crosslinking agent 1,1-bis(tert-amylperoxy)cyclohexane, 0.02 parts of co-crosslinking agent trimethylolpropane Acrylates, 0.8 parts of the first cross...

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Abstract

The invention provides a co-extrusion adhesive film, a solar battery module and double-layer glass. The co-extruded adhesive film includes at least two adhesive film layers, and the raw materials forming each adhesive film layer include the first component and the second component by weight, and the first component is 1 to 100 parts grafted with electron-withdrawing groups. The first matrix resin of the group, the second components each independently contain 0.01 to 25 parts of water producing agent and / or 0.01 to 2.5 parts of catalyst, and each second component is not simultaneously a water producing agent or a catalyst, the first A cross-linking reaction can occur between the matrix resin and the water generating agent, and the catalyst can catalyze the cross-linking reaction. When the above-mentioned co-extrusion film is used as a raw material to prepare a solar cell module, its photoelectric conversion efficiency can be greatly improved, and the cost is low, the process is simple, and it is convenient for industrialization.

Description

technical field [0001] The invention relates to the field of solar cell manufacturing, in particular to a co-extrusion adhesive film, a solar cell module and double-layer glass. Background technique [0002] In solar modules, the photovoltaic co-extrusion film is the only "barrier" between the silicon wafer and the outer glass. In order to ensure the high photoelectric conversion efficiency of the solar module, the co-extrusion film needs to have excellent barrier properties, Creep properties, etc., and the above properties of photovoltaic co-extrusion film are closely related to its cross-linking degree. In addition, in order to avoid glue overflow during the lamination process, it is necessary to reduce the fluidity of the film during lamination. Generally, the fluidity of the film is controlled by adjusting the pre-crosslinking degree of the film. [0003] At present, film crosslinking generally adopts the following methods: chemical crosslinking, radiation crosslinking,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/10C09J7/30C09J151/06C09J123/36C09J123/08C09J123/32C09J123/26C09J11/06C09J11/04C03C27/12H01L31/048
CPCC09J7/10C09J7/30C09J151/06C09J123/36C09J123/0815C09J123/32C09J123/26C09J11/06C09J11/04H01L31/0481H01L31/0488B32B17/06B32B7/12C08L2205/03C08L2205/025C08L2203/204C08K2003/3045C08K2003/2206C09J2203/322C08L23/0853C08K5/14C08L23/0815C08K3/30C08K5/053C08K13/02C08K3/22C08K5/09C08L23/26C08K5/00Y02E10/50
Inventor 魏梦娟唐国栋周光大
Owner HANGZHOU FIRST APPLIED MATERIAL CO LTD