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Coal-fired flue gas desulfurization, denitrification and foam inhibition catalytic synergist and use method thereof

A technology for desulfurization and denitrification, coal-fired flue gas, applied in chemical instruments and methods, separation methods, gas treatment, etc., can solve the problems of easy fouling and clogging and air bubbles in the desulfurization system, reduced reliability of the desulfurization system, and low desulfurization and denitrification efficiency. , to achieve the effects of shortening the half-ablation time of limestone, improving the adaptability of sulfur content, and saving consumption

Inactive Publication Date: 2020-08-25
河北丰强科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Therefore, in order to protect the environment and make the flue gas discharge meet the emission standards, it is necessary to desulfurize and denitrify the boiler flue gas. In the prior art, when the magnesium method and the limestone gypsum wet desulfurization system are used for desulfurization and denitrification, a large amount of limestone is often consumed , the overall desulfurization and denitrification efficiency is not high, and the desulfurization system is also prone to fouling, blockage and air bubbles during the desulfurization and denitrification process, which reduces the reliability of the desulfurization system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Embodiment 1: a kind of coal-fired flue gas desulfurization and denitrification anti-foaming catalytic synergist, specifically comprises the raw material of following mass percent: 10% co-solvent, 40% oxidation catalyst, 30% co-activator, 10% retarder Scale inhibitor, 8% co-dispersant and 2% assay conditioner.

[0019] Wherein, the co-solvent is composed of 20% succinic acid, 30% adipic acid and 50% citric acid. The oxidation catalyst consists of 35% ethylenediaminetetraacetic acid, 25% vanadium oxide and 40% manganese sulfate. The scale and foam inhibitor consists of 40% polyacrylic acid, 50% dodecyl benzyl ammonium chloride and 10% polyether modified silicon. The auxiliary dispersant consists of 45% sodium polyacrylate and 55% carboxymethyl cellulose. The analysis regulator uses sodium bromide. The coactivator consists of 33% sodium sulfate, 37% sodium lignosulfonate and 30% acrylamide.

[0020] A method for using a catalytic synergist for desulfurization and deni...

Embodiment 2

[0021] Embodiment 2: a kind of coal-fired flue gas desulfurization and denitrification anti-foaming catalytic synergist, specifically comprises the raw material of following mass percent: 80% co-solvent, 5% oxidation catalyst, 5% co-activator, 4% retarder Scale inhibitor, 5% co-dispersant and 1% analytical conditioner.

[0022] Wherein, the co-solvent is composed of 30% citric acid, 43% glutaric acid and 27% benzoic acid. The oxidation catalyst consisted of 25% ethylenediaminetetraacetic acid, 35% magnesium oxide and 40% calcium sulfate. The anti-scaling and anti-foaming agent is made up of 15% polyacrylic acid, 16% sodium dodecyl benzene cyclic acid, 35% aminotrimethylene phosphoric acid, 14% polysiloxane and 20% polyethylene glycol . The auxiliary dispersant is polyacrylic acid. Potassium bromide is used as the analytical regulator. The coactivator consists of 55% formamide and 45% sodium alginate

Embodiment 3

[0023] Embodiment 3: a kind of coal-fired flue gas desulfurization and denitrification anti-foaming catalytic synergist, specifically comprises the raw material of following mass percent: 50% co-solvent, 30% oxidation catalyst, 17.9% co-activator, 1% retarder Scale inhibitor, 1% co-dispersant and 0.1% analytical conditioner.

[0024] Wherein, the co-solvent is composed of 15% succinic acid, 13% adipic acid, 27% citric acid, 25% glutaric acid and 20% benzoic acid. The oxidation catalyst is composed of 14% EDTA, 13% vanadium oxide, 17% magnesium oxide, 16% magnesium sulfate, 11% manganese sulfate, 16% calcium sulfate and 13% potassium persulfate composition. Described antiscaling antifoaming agent is made of 9% polyacrylic acid, 11% dodecyl benzyl ammonium chloride, 17% sodium dodecylbenzenecycloate, 13% aminotrimethylene phosphoric acid, 8% It is composed of polyether modified silicon, 12% polysiloxane and 30% polyethylene glycol. The auxiliary dispersant consists of 35% sod...

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PUM

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Abstract

The invention discloses a coal-fired flue gas desulfurization, denitrification and foam inhibition catalytic synergist and a use method thereof. The catalytic synergist comprises the following raw materials in percentage by mass: 10-80% of a cosolvent; 5-40% of an oxidation catalyst; 5-30% of a co-activator; 1-10% of a scale and foam inhibitor; 1-10% of a co-dispersant; and 0.1-2% of an analysis regulator. With the coal-fired flue gas desulfurization, denitrification and foam inhibition catalytic synergist is adopted, desulfurization and denitrification efficiency can be improved; the semi-ablation time of limestone is reduced; the dissolution speed of the limestone is obviously accelerated; the activity of limestone can be greatly improved; the fluctuation of the PH value of slurry is mitigated; the liquid-gas ratio L / G of a system is reduced; the resistance of a spraying layer is reduced; the utilization efficiency of oxidation air is improved; the consumption of a booster fan is reduced; the Ca / L ratio of the system is reduced; the consumption of the limestone is reduced; the dispersity of the limestone is improved; calcium sulfite oxidation is promoted; scaling blockage and foaming of a desulfurization system are reduced; and the reliability of the desulfurization system is improved.

Description

technical field [0001] The invention relates to the technical field of desulfurization and denitrification of coal-fired flue gas, in particular to a catalytic synergist for desulfurization and denitrification of coal-fired flue gas and a use method thereof. Background technique [0002] The boiler flue gas has the largest content of soot and sulfur dioxide, followed by carbon monoxide, hydrocarbons, nitric oxide and photochemical smog. Most of these pollutions come from various industrial boilers, power plant boilers and civil boilers that burn coal. The sulfur content in coal is generally 0.5%-4%, and some are as high as 8%. When coal is burned, sulfur in coal reacts with oxygen to produce sulfur dioxide gas. When the concentration of sulfur dioxide in the air is greater than 0.1ppm, it will damage or corrode plants and equipment. In addition, hydrocarbons such as nitric oxide and methane in the flue gas are irradiated by ultraviolet rays in the sun to produce light blue...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/80B01D53/50
CPCB01D53/502B01D53/80B01D2251/404B01D2251/604B01D2258/0283
Inventor 张建辉肖瑞莲
Owner 河北丰强科技有限公司
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