The invention relates to a photolysis-resistant pesticide and application thereof. The photolysis-resistant pesticide comprises the following components in percentages in weight: 0.1-90 percent photosensitive pesticide active ingredient, 0.2-30 percent water-soluble ultraviolet absorbent, 0.2-20 percent oil-soluble ultraviolet absorbent, 0.2-20 percent antioxidant, 1-20 percent surfactant and 4-95 percent solvent or carrier. According to the photolysis-resistant pesticide, the water-soluble ultraviolet absorbent and the oil-soluble ultraviolet absorbent are adopted for synergistic effect, and simultaneously the antioxidant is added; and therefore, at least 30 percent, even more than 50 percent, ultraviolet light can be absorbed, the photolysis-resistance of the photosensitive pesticide active ingredient can be improved, and the half-life of the pesticide can be prolonged; namely, the exposure durations of pests (bacteria, weeds or mites and the like) under the pesticide atmosphere are increased, the using effect of the pesticide is enhanced, and the use amount of the pesticide is reduced; and the photolysis-resistant pesticide can be used for preventing and controlling various pests and diseases of plants, especially crops.