39 results about "Liquid metal embrittlement" patented technology

The present invention relates to a plated steel sheet having a plated layer with excellent stability for hot press molding, and more specifically, to a plated steel sheet having a plated layer with excellent stability for hot press molding in which a LME (Liquid Metal Embrittlement) phenomenon caused by a zinc enrichment region included in the plated layer is suppressed during hot press molding.

A hot-dip galvanized steel sheet having excellent resistance to cracking caused by liquid metal embrittlement is provided. The hot-dip galvanized steel sheet having excellent resistance to cracking caused by liquid metal embrittlement includes a base steel sheet having a microstructure in which an austenite fraction is 90 area % or more; and a hot-dip galvanizing layer formed on the base steel sheet, wherein the hot-dip galvanizing layer includes an Fe—Zn alloy layer; and a Zn layer formed on the Fe—Zn alloy layer, and the Fe—Zn alloy layer has a thickness of [(3.4×t)/6]μm or more, where t is a thickness of the hot-dip galvanizing layer. In addition, provided is the hot-dip galvanized steel sheet in which plating layer delamination easily occurring in vehicle welding and molding conditions according to the related art, is prevented, and cracking caused by liquid metal embrittlement is suppressed.

Methods of strengthening surface regions of high-strength transformation induced plasticity (TRIP) steel are provided. The method may comprise shot peening at least one region of an exposed surface of a hot-formed press-hardened component comprising a high-strength steel. Prior to shot peening, the component has a microstructure comprising >=about 5% by volume retained austenite in a matrix of martensite. The shot peening is conducted at a temperature of <about 150DEG. and forms at least one hardened surface region comprising <=about 2% by volume austenite. The TRIP steel may be zinc-coated and having a surface coating comprising zinc and substantially free of liquid metal embrittlement (LME). Zinc-coated hot-formed press-hardened components, including automotive components, formed from such methods are also provided.

The invention discloses an aluminum-rich series zinc-based plating layer material capable of reducing brittleness caused by liquid metal in a hot forming process and a preparation method thereof. A Zn-Al-Mg alloy plating layer is prepared by mainly adjusting the content of Al and Mg in a plating solution and controlling the content proportion of the Al to the Mg, and the Zn-Al-Mg alloy plating layer comprises the following components including, by mass, 0.2%-5% of Al, less than or equal to 2.5% of Mg, 0-2% of Si, 0-1% of Ti, 0-3% of RE and the balance Zn and some inevitable impurities, wherein the RE is at least one element of La and Ce. According to the method, plating layer materials with different element contents are prepared for a 22MnB5 steel plate; and through a plating layer preparation-hot dipping experiment, austenitizing treatment, plating layer and steel plate structure observation and steel plate hot tensile experiment detection, the material has the performance of inhibiting liquid metal embrittlement and high corrosion resistance, the problem of embrittlement caused by the liquid metal in the hot stamping forming process of the high-strength steel plate plated with the aluminum-rich zinc-based plating layer is solved, the corrosion resistance of the plating layer is achieved, and the oxidation problem of the plating solution in the hot dipping process is solved.

A method for producing an arc-welded Zn—Al—Mg alloy coated steel plate structural member excellent in liquid metal embrittlement cracking resistance is provided. The method contains a step of joining steel members by gas-shielded arc-welding to produce a welded structural member, at least one of the steel members to be used is a hot dip Zn—Al—Mg alloy coated steel plate member, and the shield gas contains an Ar gas, a He gas or an Ar—He mixed gas as a base gas with a CO₂ concentration controlled in a range of from 0 to 7% by volume.

[Problem] To produce a hot-dip Zn—Al—Mg alloy coated steel sheet that is excellent in coating adhesion, by using, as a base sheet for coating, a steel sheet that is imparted with resistance to liquid metal embrittlement cracking by adding B.

[Solution] A hot-dip zinc alloy coated steel sheet excellent in coating adhesion containing at least one of a Si simple oxide, a Mn simple oxide, a Cr simple oxide, a Si—Mn composite oxide, a Si—Cr composite oxide, a Mn—Cr composite oxide, and a Si—Mn—Cr composite oxide in a portion within 10 μm from an interface between a steel sheet as a base sheet for coating, and a hot-dip galvanized layer formed on a surface thereof.

A resistance spot welding method of galvanized high-strength steel with good joint performance, wherein: three welding pulses are used within one spot welding schedule; a first welding pulse and a second welding pulse are used for generating a nugget and suppressing the generation of liquid metal embrittlement (LME) cracks, wherein the first welding pulse generates a nugget having a diameter of 3.75T½-4.25T½ in which T represents a plate thickness; the second welding pulse causes the nugget to grow slowly; and a third welding pulse which is a tempering pulse is used for improving plasticity of a welding spot. A time t1 of the first welding pulse is set and a welding current I1 of the first welding pulse is obtained through tests, and the welding current I1 of the first welding pulse is a welding current upon generating the nugget having the diameter of 3.75T½-4.25T½; and a welding current I2 and a time t2 of the second welding pulse, and a welding current I3 and a time t3 of the third welding pulse are calculated by the welding current I1 and the time t1 of the first welding pulse. By the resistance spot welding method of galvanized high-strength steel, the liquid metal embrittlement cracks during the spot welding of the high-strength steel galvanized plates can be effectively suppressed, meanwhile, the plasticity of the welding point is improved, and the probability of button pullout failure of the welding point during broken testing is increased. Therefore, the joint by spot welding of the high-strength steel galvanized plates with more reliable quality and more excellent performance is obtained, and a useful guidance can be provided for the welding production of the high-strength steel galvanized plates.

A method for producing a zinc or zinc-alloy coated steel sheet with a tensile strength higher than 900 MPa, for the fabrication of resistance spot welds containing in average not more than two Liquid Metal Embrittlement cracks per weld having a depth of 100 μm or more, with steps of providing a cold-rolled steel sheet, heating cold-rolled steel sheet up to a temperature T1 between 550° C. and Ac1+50° C. in a furnace zone with an atmosphere (A1) containing from 2 to 15% hydrogen by volume, so that the iron is not oxidized, then adding in the furnace atmosphere, water steam or oxygen with an injection flow rate Q higher than (0.07%/h×α), α being equal to 1 if said element is water steam or equal to 0.52 if said element is oxygen, at a temperature T≥T1, so to obtain an atmosphere (A2) with a dew point DP2 between −15° C. and the temperature Te of the iron/iron oxide equilibrium dew point, then heating the sheet from temperature T₁ up to a temperature T₂ between 720° C. and 1000° C. in a furnace zone under an atmosphere (A2) of nitrogen containing from 2 to 15% hydrogen and more than 0.1% CO by volume, with an oxygen partial pressure higher than 10⁻²¹ atm., wherein the duration t_D of heating of the sheet from temperature T₁ up to the end of soaking at temperature T₂ is between 100 and 500s., soaking the sheet at T₂, then cooling the sheet at a rate between 10 and 400° C./s, then coating the sheet with zinc or zinc-alloy coating.

A method to mitigate liquid metal embrittlement cracking in resistance welding of galvanized steels includes modifying at least one face of a steel member to create a first workpiece by: applying a zinc containing material in a first layer to the at least one face of the steel member; and spraying a second layer of a copper containing material onto the first layer of the zinc containing material. The at least one face of the first workpiece is abutted to a second workpiece of a steel material. A resistance welding operation is performed to join the first workpiece to the second workpiece. A temperature of the resistance welding operation locally melts the zinc containing material and the copper containing material to create a brass alloy of the zinc containing material and the copper containing material.

A system and method for cooling a heat exchanger.

The present invention relates to a method for the manufacture of a coated steel sheet comprising the following successive steps: A. the coating of the steel sheet with a first coating consisting of nickel and having a thickness between 600 nm and 1400 nm, the steel sheet having the following composition in weight: 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<3.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0%, and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.010%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B. the recrystallization annealing at a temperature between 820 to 1200° C., C. the coating with a second coating based on zinc not comprising nickel.

Provided is a steel sheet having excellent resistance to liquid metal embrittlement cracks and a method for manufacturing the same. The steel sheet includes, by weight %: 0.04% to 0.35% of C, 0.99% or less of Al+Si, 3.5% to 10% of Mn, 0.05% or less of P(excluding 0%), 0.02% or less of S(excluding 0%), and 0.02% or less of N (excluding 0%) with a remainder of Fe and other inevitable impurities, wherein the steel sheet comprises a microstructure comprising at least 10% of residual austenite, at least 60% of annealed martensite and 20% or less of alpha martensite and epsilon martensite, by volume fraction, and an average thickness of a Mn-depleted layer is at least 0.5 μm from a product surface.

A high temperature substrate coating to mitigate liquid metal embrittlement (LME) cracking in automobile vehicles includes a substrate. A coating is disposed on the substrate, the coating being one of a zinc-based material and an aluminum-based material, with the coating having a melting point of at least 500° C.

A multi-material component joined by a high entropy alloy is provided, as well as methods of making a multi-material component by joining materials with high entropy alloys to reduce or eliminate liquid metal embrittlement (LME) cracks.