The invention discloses a method of preparing ultrafine silica from
chlorosilane residual liquid, and belongs to the technical field of treatment and
recovery of
chlorosilane residual liquid. The preparation method comprises the following steps: buffering
chlorosilane residual liquid in a residual
liquid storage tank,
settling impurities in the tank, introducing the processed chlorosilane residual liquid to a
hydrolysis tower, carrying out atomization by taking the
nitrogen gas as the atomization gas source, contacting a prepared acidic absorber with the atomized chlorosilane residual liquid to carry out reactions, introducing the obtained
mixed solution absorbed by
hydrolysis reactions into a sealed intermediate collecting groove; subjecting the absorbed
mixed solution to
solid-liquid separation, delivering the separated
hydrochloric acid, which can be used to prepare the absorber, to a
hydrochloric acid storage tank; washing the separated silica to remove the
hydrochloric acid and part of
metal impurities, wherein the acid-containing water generated during the washing process can be used to prepare the absorber; and finally
drying the washed silica so as to obtain the finished product of ultrafine silica. The
nitrogen gas atomization is carried out under a sealed condition, and the provide method has the advantages of safety, reliability, low
energy consumption, and no
pollution, and converts the chlorosilane residual liquid into valuable resource.