The invention relates to the technical field of
laser gain material synthesis, in particular to a low-threshold
quantum dot
laser gain film and a preparation method thereof. Comprising the following steps: in an
inert gas
atmosphere, preparing a
zinc oleate precursor solution, a
cadmium oleate precursor solution, a tri-n-octylphosphine-
selenium precursor solution and a tri-n-octylphosphine-
sulfur precursor solution; preparing a
mixed solution on site, including a
mixed solution A, a
mixed solution B and a mixed solution C; preparing the core-shell
quantum dots by adopting a step-by-step thermal injection method, namely preparing a core, a continuous gradient layer and a protective layer; purifying the core-shell
quantum dots by using a purifying agent, and performing post-treatment to form a dispersion liquid; and spin-
coating the dispersion liquid to a substrate by adopting a one-step spin-
coating method, and annealing to form the low-threshold
quantum dot laser gain film. The
quantum dot core-shell material has the advantages that the prepared
quantum dot core-shell material has a gradient
energy level gradient structure, the quantum dots can obtain a smooth constraint potential barrier from the core to the shell through the gradient structure, non-radiative recombination of the quantum dots is improved, and the laser performance of the material is improved, namely the ASE threshold value of the quantum dots is reduced.