The invention discloses a torque vector control system of a hub four-wheel drive purely-electric vehicle. The torque vector control system comprises a vehicle state monitor, a friction coefficient estimator, a differential torque yawing moment decision making module, a torque control distributor module and a torque coordination control module. The differential torque yawing moment decision makingmodule is used for acquiring vehicle differential torque yawing moment by establishing a kinematics parameter relationship according to the driver input steering wheel rotating angle, vehicle motion information, the road surface adhesion coefficient, lateral tire force and longitudinal tire force. The torque control distributor module is used for acquiring ideal torque distributed values of all wheels according to four-wheel hub motor brake and drive torque requirements, the vehicle motion information, the road surface adhesion coefficient, tire parameter information, the battery SOC value anddifferential torque yawing moment. The control stability of the vehicle can be improved, and the steering sensitivity of the vehicle can be improved.