The invention relates to a Cs3Bi2I9 single-
crystal material with double
heat transfer operation parameters as well as a preparation method and application thereof, and belongs to the technical field of single-
crystal materials. The preparation method comprises the following steps: uniformly mixing and
grinding CsI and BiI3 according to a stoichiometric ratio, transferring into a
quartz tube, vacuumizing and packaging, and sequentially carrying out high-temperature melting,
quenching and annealing to obtain a Cs3Bi2I9 polycrystalline cast
ingot of which the density is not less than 97%; placing the Cs3Bi2I9 polycrystalline cast
ingot in a sealed
quartz tube, placing the sealed
quartz tube in which the Cs3Bi2I9 polycrystalline cast
ingot is packaged in a vertical
temperature gradient furnace, melting at high temperature, and cooling to
room temperature, thereby obtaining the Cs3Bi2I9
single crystal material with the double
heat transfer operation mode. Compared with the prior art, the Cs3Bi2I9
single crystal material with a unique double-heat transport behavior is innovatively prepared, a new design idea is provided for regulating and controlling heat transport through a
crystal chemical means, and a new path is opened up for developing an anisotropic thermoelectric material with a
heat management function.