The invention discloses a synergistic pesticide composition and application thereof. The active components of the synergistic pesticide composition are flufiprole and carbamate pesticide, wherein the carbamate pesticide is one of fenobucarb, isoprocarb, carbosulfan, carbaryl, metolcarb, methomyl, pirimicarb and thiodicarb. The weight ratio of the flufiprole to the carbamate pesticide is (1:50) - (1:1), and the weight percentages of the flufiprole and the carbamate pesticide in the composition are both 2-80%. The synergistic pesticide composition is applied to preventing and controlling agricultural pests. Through the application of the synergistic pesticide composition, the control efficiency is obviously improved as compared with that of single dosage, the use amount of the pesticide is reduced, the influence of pesticide on environment is reduced, and the pesticide cost is lowered.