20 results about "Cyantraniliprole" patented technology

The invention relates to the technical field of pesticides, in particular to a pesticide composition, application thereof and a pesticide preparation. The pesticide composition comprises a first effective component and a second effective component, the first effective component is 1, 8-cineole, and the second effective component comprises at least one of flonicamid, cyantraniliprole, nitenpyram, flubendiamide, spirotetramat, pyriproxyfen, pymetrozine, dinotefuran and sulfoxaflor. The mass ratio of the first effective component to the second effective component is (50: 1)-(1: 100). Through the synergistic interaction of the first effective component and the second effective component, the prevention and treatment effect is remarkably improved, the prevention and treatment spectrum is expanded, and the field dosage can be greatly reduced; specifically, leaf back bemisia tabaci and trialeurodes vaporariorum can be well controlled, the control effect on bemisia tabaci, trialeurodes vaporariorum, thrips and the like is improved, and the application prospect is good.

The present invention relates to the preparation of cyantraniliprole, comprising the preparation of 8-methyl-2,4-dioxo-1,4-dihydro-2H-benzo[d][1,3]oxazine-6-carbonitrile key intermediate via 2-amino-5-((hydroxyimino)methyl)-3-methylbenzoic acid. Wherein hydroxylamine attacks a benzylic formyl group, to obtain the 2-amino-5-((hydroxyimino)methyl)-3-methylbenzoic acid, that undergoes simultaneously or by consecutive steps dehydrogenation and cyclization to obtain the benzo[d][1,3]oxazine group and the cyano group of the desired product. In addition, an improved method for the synthesis of the benzylic formyl group is also displayed.

The present invention relates to solid water dispersible compositions comprising particulate acetamiprid and paniculate cyantraniliprole characterized by spontaneous and fast disintegration, producing physically stable suspensions of particulate cyantraniliprole in aqueous solutions of acetamiprid, with low agglomeration formation or particle size growth and minimal persistent foam. The present invention also relates to methods of use and process of preparing the solid composition comprising acetamiprid and cyantraniliprole.

The present invention relates to the process of preparation of cyano-benzene derivatives including cyantraniliprole, comprising the preparation of cyano-group via cyanation reagent, wherein the cyanation reagent reacts with benzene derivatives, to form the cyano-benzene derivatives. The present invention provides one-step, high yield, high efficiency, and low-cost cyanation synthesis of cyano substituted substances including common pesticides such as cyantraniliprole.

The application provides an intermediate for synthesizing chlorantraniliprole and cyantraniliprole and a preparation method of the intermediate, and the structural formula of the intermediate is 2-amino-3-methylbenzoic acid. The intermediate is obtained by a -D-A reaction, aromatization and a Hoffmann elimination reaction from a cheap bio-based platform compound 2-methylfuran as a starting material. The whole process does not need a dangerous nitration process and a hydrogenation process, the process has mild reaction conditions, good operability, less wastewater and a high yield of the obtained intermediate, and is very suitable for industrialized preparation of an intermediate required by the high-efficiency insecticides chlorantraniliprole and cyantraniliprole.

The invention relates to a chlorantraniliprole hapten, a complete antigen and application of the chlorantraniliprole hapten and the complete antigen. When the chlorantraniliprole artificial antigen and the monoclonal antibody are used for ELISA detection, the specificity is high, the IC50 value is 0.058 [mu] g / L, the detection limit of chlorantraniliprole in a standard solution reaches 0.6 [mu] g / L, and the detection limit of a sample to be detected reaches 2 g / kg; the cross reaction rates with cyantraniliprole, tetrachlorantraniliprole and cyclaniliprole are respectively 20%, 12% and 12%, and the material specificity is greatly improved. By utilizing the chlorantraniliprole hapten, the complete antigen and the antibody, the purpose of rapidly and accurately detecting chlorantraniliprole in a sample can be achieved.

The application belongs to the technical field of pesticide insecticide, and discloses a pesticide composition containing brofenvalerate, which comprises active ingredient A, active ingredient B and active ingredient C; the active ingredient A is brofenvalerate; the active ingredient B is high-efficiency lambda-cyhalothrin; and the active ingredient C is any one of thiamethoxam or thiamethoxam. The pesticide composition can effectively prevent and control various underground pests and seedling stage pests, especially the underground pests and seedling stage pests of peanuts and corns, and can enhance the stress resistance of plants, reduce the amount of pesticide, prolong the effective period, and has no pesticide damage to crops.

This invention relates to a method of controlling, limiting or preventing an infestation of a plant by Oomycetes, which comprises applying to propagation material of said plant, a pesticidal combination comprising a phosphorus-based compound as active ingredient A, and an active ingredient B selected from acibenzolar-S-methyl, fludioxonil, fluxapyroxad, inpyrfluxam, mefentrifluconazole, prothioconazole, sedaxane, triticonazole, oxathiapiprolin, fluoxapiprolin, azoxystrobin, difenoconazole, fluopyram, ipconazole, metyltetraprole, silthiofam, dimethomorph, thiophanate-methyl, natamycin, benzovindiflupyr, pydiflumetofen, picarbutrazox, isocycloseram, cyclobutrifluram, broflanilide, thiamethoxam, imidacloprid, clothianidin, cyantraniliprole, chlorantraniliprole, tetraniliprole, fipronil, and any mixture thereof.

The invention belongs to the field of pesticides, and provides a cyantraniliprole synergistic composition and an application of the cyantraniliprole synergistic composition, and the cyantraniliprole synergistic composition comprises cyantraniliprole and an enzymolysis yellow tube vegetable protein. According to the application, the harmful seaweed yellow tube vegetable extracted protein is used for synergism of cyantraniliprole, so that the application amount and the application frequency of cyantraniliprole can be effectively reduced, the cost is saved, and the green and environment-friendly requirements are met.

The present invention relates to the preparation of cyano-anthranilic acid derivatives from 2-amino-5-formyl-3-methylbenzoic acid derivatives, including 2-amino-5-cyano-3- methylbenzoic acid, in the presence of N-methylpyrrolidone (NMP), N,N- dimethylformamide (DMF), N,N-dimethylacetamide (DMA), dimethylsulfoxide (DMSO), and the mixtures thereof, used as a dehydration agent. The present invention discloses an efficient, high yield process to obtain cyano-anthranilic acid intermediate further leading to the manufacturing of diamides, in particular, cyantraniliprole.

Pesticidal mixtures comprising as active compounds A) the ethylsulfone compound of formula (I) and B) at least one further compound B selected from fipronil, lambda-cyhalothrin, bifenthrin, tefluthrin, alpha-cypermethrin, thiamethoxam, clothianidin, acetamiprid, imidacloprid, dinotefuran, tri-flumezopyrim, fenmezoditiaz, spinosad, spinetoram, abamectin, afidopyropen, indoxacarb; met-aflumizone, spiropidion, spidoxamat, chlorantraniliprole, cyantraniliprole, tetraniliprole, cyclaniliprole, broflanilide, isocycloseram; dimpropyridaz; and difenoconazole, prothioconazole, flutriafol, ipconazole, tebuconazole, mefentrifluconazole, triticonazole, fluoxytioconazole, metyltetraprole, azoxystrobin, trifloxystrobin, pyraclostrobin, sedaxane, penflufen, fluopyram, fluxapyroxad, pydiflumetofen, isoflucypram, cyclobutrifluram, oxathiapiprolin, fluoxapriprolin, metalaxyl, picarbutrazox, fludioxonil, thiophanat-methyl; methods and use of these mixtures for combating invertebrate pests such as insects, arachnids or nematodes in and on plants, and for protecting such plants being infested with pests, especially also for protecting plant propagation material as like seeds.

This invention relates to a method of controlling, limiting or preventing an infestation of a plant by Oomycetes, which comprises applying to propagation material of said plant, a pesticidal combination comprising a phosphorus-based compound as active ingredient A, and an active ingredient B selected from acibenzolar-S-methyl, fludioxonil, fluxapyroxad, inpyrfluxam, mefentrifluconazole, prothioconazole, sedaxane, triticonazole, oxathiapiprolin, fluoxapiprolin, azoxystrobin, difenoconazole, fluopyram, ipconazole, metyltetraprole, silthiofam, dimethomorph, thiophanate-methyl, natamycin, benzovindiflupyr, pydiflumetofen, picarbutrazox, isocycloseram, cyclobutrifluram, broflanilide, thiamethoxam, imidacloprid, clothianidin, cyantraniliprole, chlorantraniliprole, tetraniliprole, fipronil, and any mixture thereof.

The present application relates to a synergistic composition containing a biologically effective amount of compound A and component B, wherein the component B is one of thiazide ketone, avermectin, spirotetramat, pyridalyl, emamectin benzoate, azamethiphos, azocyclotin, pyridaben, quimacryd thiocyl, pyrimidifen, tebufenpyrad, flufenoxuron, chlorfenapyr, cyromazine, and halofenozide, and a method thereof for controlling pests in agronomic and non-agronomic environments. The compound A has a synergistic effect with the component B, which can improve the pest control effect, reduce the application amount, reduce the use frequency, and reduce the use cost.

The application discloses a new crystal form of brofenvalerate, a preparation method and application thereof. The new crystal form of brofenvalerate comprises a powder X-ray diffraction spectrum expressed by 2θ±0.2° diffraction angle, and the powder X-ray diffraction spectrum shows characteristic peaks at 8.70, 9.94, 11.24, 12.24, 22.38 and 24.70. Compared with the existing crystal form of brofenvalerate, the new crystal form of brofenvalerate discovered by the application has a simple preparation method, more excellent properties and higher biological activity, and can be used for the prevention and control of pests of the orders Lepidoptera, Hemiptera, Coleoptera, Thysanoptera, Hymenoptera, Acarina and Diptera.

The present application relates to a kind of insecticidal composition and its application, it is related to the field of pesticide, the effective component of insecticidal composition includes carbamate compound and amide insecticide, and its weight ratio is (1-50) :(1-50);The carbamate compound is selected from one or several of thiodicarb, fenobucarb, fenoxycarb and propetamphos;The amide insecticide is selected from one or several of broflan, cyhalofop-butyl, chlorantraniliprole;Carbamate compound of the present application can be used as the internal absorption of amide insecticide Conducting agent, greatly improve the absorption and transmission amount of amide insecticide in crop, improve the insecticidal effect of amide insecticide, improve the utilization rate of pesticide, reduce environmental pollution.

The present invention relates to new solid forms of cyantraniliprole, processes for its preparation, and agrochemical compositions thereof.

A synergistic insecticidal composition comprising (A) isothiazolyl amide; (B) one insecticide selected from the group consisting of chlorantraniliprole, cyantraniliprole, cyclaniliprole, tetraniliprole, pyridalyl, pymetrozine, chlorfenapyr, sulfoxaflor, flubrocythrinate, sulfoxaflor; and (C) one or more insecticides selected from the given list. The invention also relates to a process for the preparation of said composition in specific amounts. The invention also relates to a process for the preparation of said composition together with at least one formulation excipient, and to the formulation of said composition. The invention also relates to a synergistic composition, wherein the active ingredients present in fixed amounts exhibit a synergistic effect in terms of insecticidal activity.

A mixture for killing pests, comprising, as the active compound, A) an ethyl sulfone compound having formula (I) and B) At least one additional compound B, selected from fipronil, λ-cyhalothrin, bifenthrin, heptafluthrin, α-cyhalothrin, thiamethoxam, thiamethoxam, acetamiprid, imidacloprid, dinotefuran, trifluralin, dithiamethoxam, spinosad, ethyl spinosad, abamectin, bispyribac-methyl, indoxacarb; cyfluthrin, methoxypiperazine ethyl ester, dispirenil, chlorantraniliprole, brofenoxuronamide, tetrazolium acetonitrile, cyclobromhizobium acetonitrile, brofenoxuron dimethoate; pyrimethanil, M.UN.1: 1-[6-(2,2-difluoro-7-methyl-[1,3]m-dioxacyclopenten[4,5-f]benzimidazol-6-yl)-5-ethylsulfonyl-3-pyridyl]cyclopropaneformonium, M.UN.2: 6-(5-cyclopropyl-3-ethylsulfonyl- 2-pyridyl)-2,2-difluoro-7-methyl-[1,3]m-dioxacyclopenten[4,5-f]benzimidazole; and difenoconazole, prothioconazole, fenbendazole, tebuconazole, chlorfluazuron, cymoxanil, fluopyram, tetrazoxystrobin, azoxystrobin, oxadiazon, azoxystrobin, fluopyram, fluopyram, fluopyram, fluopyram, fluopyram, isopropoxystrobin, trifluoropyridamole, fluthiazolinone, flusaprolin, metalaxyl, tetrazoxystrobin, fludioxonil, thiophanate-methyl; these mixtures are used to combat invertebrate pests such as insects, arachnoides or nematodes inside and on the surface of plants, and for the protection of such plants, especially for the protection of plant propagation material such as seeds from pest infestation.

The present invention relates to a method of controlling, limiting or preventing the infestation of plants by Ascomycota plant pathogens, which comprises applying to the plant propagation material a pesticidal combination comprising as active ingredient A a phosphorus-based compound and as active ingredient B a fungicide selected from the group consisting of acibenzolar-S-methyl, fludioxonil, fluazinam, fluindapyr, metconazole, prothioconazole, silthiofam, triticonazole, flutianil, fluorofuram, azoxystrobin, difenoconazole, pyridylcarbamate, ipconazole, tetraconazole, silthiofam, dimethomorph, thiophanate-methyl, natamycin, benzene enofluorocarbostyril, fluazinam, triflupyrrole, high efficiency metalaxyl (metamitron), tetraconazole, isoxazoles, bromofluoride, thiamethoxam, imidacloprid, clothianidin, cyantraniliprole, tioxazofen, flufenoxuron and any mixtures thereof.

The present invention provides a bisamide compound-containing pesticide composition, which comprises a first effective component and a second effective component, the first effective component is a compound having a structural formula (I), the second effective component is thiotraniliprole, chlorantraniliprole, cyantraniliprole, flubendiamide, tolfenpyrad, tetrachlorantraniliprole, cyhalodiamide, cyclaniliprole or flubendiamide, and the weight ratio of the thiotraniliprole, the chlorantraniliprole, the cyhalodiamide, the cyclaniliprole or the flubendiamide is (1-50): (1-50). The invention also provides application of the pesticide composition in prevention and control of agricultural and forestry pests, especially for chilo suppressalis, plutella xylostella and / or phyllotreta striolata. The pesticide composition has a remarkable synergistic effect, achieves the effects of improving the control effect, reducing the dosage and expanding the insecticidal spectrum, and has an excellent control effect on target pests such as chilo suppressalis, plutella xylostella, green peach aphid, beet armyworm, ostrinia nubilalis, thrips and flea beetle. (I).