The invention discloses a
thermal diode fabric for personal cooling and a preparation method thereof. The preparation method comprises the following steps: preparing a
spinning solution containing heat-conducting particles, a
hydrophobic polymer and a cross-linking agent; performing electrostatic
spinning in a low-
humidity environment to obtain a compact
heat transfer fiber membrane layer; carrying out electrostatic
spinning in a high-
humidity environment by taking the obtained compact heat-transfer
fiber membrane layer as a receiving base material to obtain a fluffy heat-insulation
fiber flocculus layer; and finally, carrying out cross-linking heat treatment to obtain the
thermal diode fabric. According to the preparation method, a simple electrostatic spinning preparation process is utilized, and the fiber material with a double-layer asymmetric density structure is prepared in one step only by regulating and controlling the
humidity under the condition that a spinning solution is not changed; the one-way heat conduction effect similar to that of a hot
diode is achieved, effective heat dissipation when the
human body is in a cold environment and effective heat insulation when the
human body is in a hot environment can be achieved, and the
skin temperature is kept under the situation that the temperature change difference is large when the
human body enters and exits an air-conditioning place in summer.