The invention discloses a remote sensing monitoring system for automotive exhaust emission of an urban road network. The system is mainly composed of a remote measurement device layer, a site selection and position arrangement layer, and a data processing layer. Through mobile, horizontal and vertical exhaust remote measurement devices, real-time data of the automotive exhaust emission in running is obtained; by adopting an advanced site selection and position arrangement method, the remote measurement devices are scientifically networked; and in combination with external data of weather, traffic, geographic information and the like, the real-time remote measurement data of the automotive exhaust emission is subjected to intelligent analysis and data mining by adopting big data processing and analysis technologies such as deep learning and the like, and key indexes and statistical data with optimal identification performance are obtained, so that effective support is provided for government departments to make related decisions.