Polymer solar cell and preparation method thereof

A solar cell and polymer technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of low charge transfer efficiency, unfavorable industrial production, affecting charge separation and transfer, etc. Mass production, effect of high electron mobility

Inactive Publication Date: 2012-05-09
东莞市万能电池实业有限公司
View PDF8 Cites 35 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still many problems in current polymer solar cells: ① The absorption spectrum does not match the solar spectrum, resulting in low utilization of sunlight; ② The light-induced electron transfer efficiency of the light-absorbing layer is low, and the charge carrier mobility is low, resulting in The charge transfer efficiency is low; ③ The aggregation and phase separation of donors and acceptors affect the separation and transfer of charges, thus affecting t...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Example 1: 5.0 g of nano-copper, 1.0 g of nano-zinc oxide and 24.0 g of deionized water were prepared into a mixed dispersion of nano-materials. Add 1.8g (0.0194mol) of aniline and 24.20mL (0.2904mol) of concentrated hydrochloric acid to the mixed dispersion of nanomaterials, stir continuously, and then add 15.48mL of 1.0M (0.01548mol) ammonium persulfate aqueous solution at -5°C. After 24 hours of oxidation polymerization, suction filtration and washing until the filtrate was colorless, the obtained slurry was the donor material. 6.0g graphene and 594.0g deionized water are made graphene dispersion liquid. Add 0.03g KH550 into the graphene dispersion, and stir continuously at 50°C for 12h to obtain a modified graphene dispersion. Add 1.8g (0.0194mol) of aniline and 24.20mL (0.2904mol) of concentrated hydrochloric acid to the modified graphene dispersion, keep stirring, and then add 15.48mL of 1.0M (0.01548mol) ammonium persulfate at -5°C After in-situ oxidative polym...

Embodiment 2

[0023] Example 2: 0.1g of nano-platinum, 0.5g of nano-silicon oxide and 11.4g of deionized water were prepared into a mixed dispersion of nanomaterials. Add 12.0g (0.1788mol) pyrrole and 24.0g (0.0684mol) sodium dodecyl sulfonate to the mixed dispersion of nanomaterials, stir continuously, and then add 662.2mL 1.35M (0.8940mol) trichlorohydrin at 50°C The ferric chloride aqueous solution was oxidized and polymerized in situ for 1 hour, then suction filtered and washed until the filtrate was colorless, and the obtained slurry was the donor material. 0.6 g of carbon nanotubes and 2.4 g of deionized water were prepared into a carbon nanotube dispersion. 0.03 g of titanate coupling agent was added to the carbon nanotube dispersion, and stirred continuously at 100° C. for 1 h to obtain a modified carbon nanotube dispersion. Add 12.0g (0.1788mol) pyrrole and 24.0g (0.0684mol) sodium dodecyl sulfonate to the modified carbon nanotube dispersion, keep stirring, then add 662.2mL1.35M (...

Embodiment 3

[0024] Example 3: 2.5g of nano-molybdenum, 2.5g of nano-crystalline copper indium gallium selenide and 50.0g of chloroform were used to prepare a nanomaterial mixed dispersion. Add 10g (0.1188mol) of thiophene to the mixed dispersion of nanomaterials, keep stirring, then add 77.1g (0.4752mol) of anhydrous ferric chloride at 20°C, and after in-situ oxidative polymerization for 12 hours, suction filter and wash until the filtrate After being colorless, the resulting slurry is the donor material. 5.0 g of fullerene and 50.0 g of chloroform were prepared into a fullerene dispersion. 0.05 g of zirconate coupling agent was added to the fullerene dispersion, and stirred continuously at 80° C. for 4 h to obtain a modified fullerene dispersion. Add 10g (0.1188mol) of thiophene to the modified fullerene dispersion, keep stirring, then add 77.1g (0.4752mol) of anhydrous ferric chloride at 10°C, perform oxidation polymerization in situ for 12 hours, and then filter with suction 1. After...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a polymer solar cell, which includes a transparent electrode, a donor material, an active layer material, a receptor material and a metal electrode, wherein a transparent base body which is covered by ITO (Indium Tin Oxide), FTO (Flouride-doped Tin Oxide), ATO (Arsenic Trioxide), graphene, carbon nanotubes or a conjugated polymer thin film is used by the transparent electrode; a nano composite material of conjugated polymer, a metal nanomaterial and a semiconductor quantum point nano material is adopted as the donor material; the active layer material is a nano composite material of conjugated polymer, graphene, carbon nanotubes or fullerene and derivatives thereof in the presence of a modifier; graphene, carbon nanotubes or fullerene and the derivatives thereof are adopted as the receptor material; and the metal electrode is made of silver paste, aluminum paste, silver aluminum paste or metal paste. The donor material, the active layer material, the receptor material and the metal paste are printed on the transparent electrode by using an ink printing machine in sequence, and are subjected to drying treatment at 50-100 DEG C in sequence to obtain the polymer solar cell. The cell has high utilization rate to sunshine, high carrier mobility, high compatibility of donor and receptor, high photoelectric conversion efficiency, simple and convenient preparation process and capability of realizing large-scale industrial application.

Description

technical field [0001] The invention relates to a polymer solar cell and a preparation method thereof. Background technique [0002] With the aggravation of the global energy crisis and environmental pollution, solar cells that convert clean renewable energy - solar energy into electrical energy - have received great attention from countries all over the world. Among all kinds of solar cells, inorganic semiconductor solar cells occupy most of the current solar cell market due to their high photoelectric conversion efficiency and mature technology. However, inorganic semiconductor solar cells have many disadvantages, such as high cost, high energy consumption, complicated manufacturing process, non-flexibility, heavy weight, and difficulty in large-scale preparation, which limit their large-scale application in many fields. [0003] Polymer solar cells can effectively solve many shortcomings of inorganic semiconductor solar cells, so they have become a hot spot in solar cell...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): H01L51/42H01L51/46C08G73/02C08G73/06C08G61/12C08K3/22C08K3/08C08K3/34H01L51/48
CPCY02E10/549
Inventor 曾永斌赖日萱曾阳生
Owner 东莞市万能电池实业有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products