The invention discloses an expiration sampling bag with an inner
coating and a multi-layer covering
film structure and a preparation method of the expiration sampling bag. The expiration sampling bag comprises a bag body and a gas inlet and outlet
assembly, and the bag body is made of a multi-layer
composite film material and sequentially comprises a double-function inner
coating, an inner-layer base material film, a first bonding layer, a core
blocking layer, a second bonding layer and an outer-layer protective film from inside to outside. The difunctional inner
coating comprises an inorganic barrier bottom layer and an organic anti-adsorption
surface layer, the core
barrier layer is an
aluminum foil layer, and a nano anchoring layer is arranged on the surface of the
aluminum foil layer. The inorganic barrier bottom layer and the organic anti-adsorption
surface layer are organically combined, so that the synergistic interaction of
gas barrier and anti-adsorption functions is realized, the adsorption quantity of VOCs on the inner surface of the bag body can be effectively reduced, the stability of the concentration of a target
analyte in an expiration sample is ensured, and the accuracy of an expiration detection result is improved.