The invention discloses a weeding composite for preventing and killing weeds in a sugarcane field. The active components of the weeding composite include trifloxysulfuron and trinexapac-ethyl which are combined based on the weight ratio of (1:0.01)-(1:100), and the weight of the active components accounts for 1-95% of the total weight of the weeding composite. The weeding composite can be wettable powder, or water dispersible granules, or a suspension agent, or an oil suspension agent, or a dry suspension agent, or powder, or granules, or missible oil, or emulsion in water, or microemulsion or suspension emulsion. The weeding composite has a remarkable weed preventing and killing effect on the sugarcane field, herbicidal activity is high, gramineae, cyperaceae and broadleaved weeds can be killed at a time, the synergism effect is remarkable, the weeding composite is safe to sugarcanes and can make sugarcanes become ripe before being harvested, the sugar degree of sugarcanes is higher, the yield increase effect is remarkable, and using cost can also be reduced.