This invention relates to 3-acyl-pentazane-2,4-diketo compound. The compound (I) has high plant growing restraining and weed killing reactivity, and shows good selectivity to the plants. It can be the weed killing solvent in the broad-leave field to remove single-leave weed. There into, R1 : H, alkyl, alkoxyl alkyl, alkylogen, alkylogen alkoxyl alkyl, substituted aromatic base and etc; R2R4: H, alkyl, alkoxyl, phenyl alkoxyl, hydroxyl alkyl, alkoxyl, alkylogen, alkylogen alkoxyl, nitryl, cyan and etc, R2, R4 can be the same or different; R3: substituted phenyl, substituted naphthyl, substituted pyridyl, substituted thiazolyl, cyan and etc.