51results about How to "The polymerization reaction conditions are mild and controllable" patented technology

The invention relates to a bi-benzene-sulfonate interface initiator and a preparing method thereof. A tertiary amine compound with bi-benzene-sulfonate anions and bi-dodecyl is synthesized, and the characteristics of a surfactant are shown; meanwhile, tertiary amine and potassium peroxodisulfate can be subjected to a redox reaction at the normal temperature, cation free radicals are formed on nitrogen atoms and then converted into carbon free radicals at adjacent positions, generating of the free radicals can be repeated, control is flexible, multi-phase concatenation polymerization is achieved, polymerization of styrene and butyl acrylate and polymerization of styrene and N,N-dimethyl acrylamide are sequentially triggered on a water / oil interface, and a multi-segmented copolymer is obtained. An experiment proves that the feeding ratio of monomer and the composition ratio of the copolymer are quite coincident, it shows that the triggering efficiency of the initiator is high, the polymerization reaction in the mode is moderate and controllable in condition and low in energy consumption, other organic solvents and emulsifiers are avoided, the product is pure, and the requirements of green chemistry are completely met.

The invention relates to a green preparing method of vinylidene fluoride / acrylic copolymer which is used as a separating membrane material. A copolymer synthetic technique is formed based on polymerization of free radicals in aqueous / oil two phase interface, a gemini type anionic surface activity initiator is specially used to be subjected to redox reaction with potassium persulfate at normal temperature, generation of free radicals in the interface is repeated for a lot of times, an independent polymerization reaction between vinylidene fluoride and acrylic acid is triggered, and a multi-segment copolymer is formed by connecting two kinds of chain segments through a initiator molecular. Experiments show that when a pH value of an aqueous-phase medium is in the range of 4.0-4.5, the material feeding ratio of a monomer coincides exactly with a component ratio of the copolymer, the content of acrylic chain segments in the copolymer is adjustable in the range of 5-25 wt.%, and the polymerization reaction in this mode is mild and controllable in condition, and low in energy consumption; meanwhile, other organic solvents and emulgators are not needed, products are pure, and the thus the preparing method of the anionic polyvinylidene fluoride membrane material totally conforms to demands for green chemistry.

The invention relates to a green preparation method of a cationic type PVDF (Polyvinylidene Fluoride) membrane material. The green preparation method is based on a copolymer synthetic technology formed by water / oil two-phase interface free radical polymerization, a Gemini type cationic surface activity initiator is specifically used so as to be in redox reaction with potassium persulfate, free radicals can be generated on an interface through multiple replication, a polymerization reaction of vinyl fluoride and dimethyl diallyl ammonium chloride is initiated, and two chain segments are connected together in series through initiator molecules to form a poly-segment copolymer. An experiment verifies that when the pH (Potential of Hydrogen) value of an aqueous medium is ranged from 4.0 to 4.5, a feed ratio of monomers and a composition ratio of the copolymer is very consistent, and the content of a dimethyl diallyl ammonium chloride chain segment in the copolymer is ranged from 5 wt percent to 25 wt percent and can be regulated; the polymerization reaction in the mode has mild and controllable condition and low energy consumption, other organic solvents and emulsifiers are not used, the product is pure, and the requirements of green chemistry are completely met.

The invention discloses polyimide with triazole rings in a main chain structure, i.e. polytriazoles imide resin and a preparation method thereof. The method comprises the following steps: firstly, designing and synthesizing binary azides; then, using binary anhydride and m-phenylacetylene as raw materials for designing and synthesizing terminal alkynyl imide compounds; and thirdly, using the terminal alkynyl imide compounds and azides with equimolar amounts to take 1, 3-Dipolar cycloaddition polymerization reaction in a solvent or adopting thermal polymerization reaction, or adopting redox catalysed polymerization for synthesizing novel polytriazoles imide. The polytriazoles imide resin prepared by the method of the invention has good processing performance, has high thermal stability, simultaneously has good mechanical property and electric performance, and embodies the characteristics of high corrosion resistance performance, high binding power and the like of the polytriazoles imide resin. The invention has wide application prospects in the fields of aviation, astronavigation, micro-electronics, automobiles, shipping industries and the like.

The invention relates to a polymerization method of reactive black dye KN-B. An amphiphilic compound containing a reactive black group and a tertiary amine structure is synthesized and can be used asan initiator for free radical polymerization, tertiary amine of the amphiphilic compound can have a redox reaction with potassium persulfate at normal temperature to generate active free radicals multiple times, the polymerization of oil-soluble monomers isoprene and the polymerization of water-soluble monomers isopropyl acrylamide can both be initiated on a water / oil interface, and therefore thepurpose of polymerizing the reactive black KN-B dye is achieved; in the mode, the functionalization and the polymerization reaction do not interfere with each other, the operation freedom degree is large, the types of products are various, the polymerization reaction conditions are mild, organic solvents or emulsifiers are not used, and the requirements for green chemistry are met.

The invention relates to a green preparation method of a vinyl chloride / butyl acrylate copolymer used as a thermoplastic elastomer. The preparation method is based on a synthesis technology of a copolymer formed by interfacial free-radical polymerization of water / oil two-phases. Based on a copolymer synthesis technology through water / oil two-phase interfacial free-radical polymerization, a polyhydroxy polyamine surface active initiator and potassium persulphate are subjected to an oxidation reduction reaction at normal temperature, free radicals are repeatedly generated on the interface and independent polymerization of vinyl chloride and butyl acrylate is initiated. Through molecules of the initiator, two chain segments are connected in series so as to form a poly-segment copolymer. It is proved through experiments that pH of an aqueous medium is within the range of 4-4.5, feed ratio of a monomer is very consistent with composition ratio of the copolymer and content of the butyl acrylate chain segments in the copolymer is adjustable within the range of 10-42wt%. According to the mode of polymerization reaction, conditions are mild and controllable, energy consumption is low, other organic solvents or emulsifiers are not used, and the product is pure. The method completely meets the requirement of green chemistry.

The invention relates to a dodecylhydrazide dication initiator and a preparation method thereof. Synthesize a compound containing dication and didodecylhydrazide, which has the characteristics of a surfactant. At the same time, the hydrazide can undergo a redox reaction with potassium persulfate at room temperature, which can repeatedly generate free radicals and flexibly control the heterogeneous series. Direct polymerization, initiating the polymerization of styrene and methyl acrylate and styrene and hydroxyethyl acrylate in sequence on the water / oil interface to obtain multi-block copolymers. Experiments have proved that the ratio of monomer feed to copolymer composition It is very consistent, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, the energy consumption is low, no other organic solvents and emulsifiers are used, and the product is pure, which fully meets the requirements of green chemistry.

The invention relates to an anionic surface active initiator and a preparation method thereof. The method comprises the steps that a tertiary amine compound containing sulfonate anion and dodecyl is synthesized, and the tertiary amine compound itself is surfactant; meanwhile, tertiary amine and potassium persulfate can be subjected to an oxidation-reduction reaction at room temperature, cationic free radicals are formed on nitrogen atoms and converted into carbon free radicals at adjacent positions, free radical generation can be repeated multiple times and controlled flexibly, multiphase concatenated polymerization of styrene and butyl acylate and styrene and acrylamide is initiated successively on a water or oil interface, and a segmented copolymer is obtained. It is provided through experiments that the feed ratio of a monomer and the component ratio of the copolymer are very consistent, it is illustrated that the initiation efficiency of the initiator is high, the polymerization reaction condition is mild and controllable, the energy consumption is low, other organic solvents and emulsifiers are not used, the product is pure, and the requirements of green chemistry are completely met.

The invention relates to a polyhydroxy polyamine surface active initiator and a preparation method thereof. Synthesize a tri-tertiary amine compound containing polyhydroxyl and hexadecyl, so that it exhibits the characteristics of a surfactant. At the same time, the tertiary amine can undergo a redox reaction with potassium persulfate at room temperature, and first form a cation on the nitrogen atom Free radicals are then converted into carbon free radicals at adjacent positions. The generation of free radicals can be repeated many times and flexibly controlled to achieve multi-phase series polymerization. Styrene and methyl acrylate and Styrene and acrylamide are polymerized to obtain corresponding multi-block copolymers. The experiment proves that the feed ratio of the monomer is very consistent with the composition ratio of the copolymer, indicating that the initiator has a high initiation efficiency, and the polymerization reaction conditions of this mode are mild. Controllable, low energy consumption, no other organic solvents and emulsifiers, pure product, fully meet the requirements of green chemistry.

The invention relates to a bisbenzenesulfonate interface initiator and a preparation method thereof. Synthesize a tertiary amine compound containing bisbenzenesulfonate anion and didodecanyl, so that it exhibits the characteristics of a surfactant. At the same time, the tertiary amine can undergo a redox reaction with potassium persulfate at room temperature. Cationic free radicals are formed on the surface, and then converted into carbon free radicals at adjacent positions. The generation of free radicals can be repeated many times, flexibly controlled, and multi-phase series polymerization is realized. Styrene and acrylic acid are initiated sequentially on the water / oil interface. Polymerization of butyl ester and styrene and N,N-dimethylacrylamide to obtain a multi-block copolymer. Experiments have proved that the feed ratio of the monomer is very consistent with the composition ratio of the copolymer, indicating that the initiator has a higher initiation efficiency. , the polymerization reaction conditions of this mode are mild and controllable, the energy consumption is low, no other organic solvents and emulsifiers are used, and the product is pure, which fully meets the requirements of green chemistry.

The invention relates to a gemini cationic surfactant initiator and a preparation method thereof. Synthesized a gemini-type amphiphilic compound containing bis-imidazolium cation and bis-isooctyl. This compound has the characteristics of emulsifying oily monomers stronger than general cationic surfactants. At the same time, the tertiary amine in the hydrophilic part can Under the redox reaction with potassium persulfate, cationic free radicals are formed on the nitrogen atom, and then converted into carbon free radicals at adjacent positions. In the direct polymerization mode, the polymerization of styrene and vinyl acetate and styrene and N-vinylpyrrolidone is initiated sequentially on the water / oil interface to obtain multi-block copolymers. The composition ratio is very consistent, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, low energy consumption, no other organic solvents and emulsifiers are used, and the product is pure, which fully meets the requirements of green chemistry.

The invention relates to a polymerization method of a reactive black KN-B dye. Synthesize an amphiphilic compound containing a reactive black group and a tertiary amine structure, which can be used as an initiator for free radical polymerization, and its tertiary amine can undergo redox reactions with potassium persulfate at room temperature to generate active free radicals many times , on the water / oil interface, both the oil-soluble monomer isoprene polymerization and the water-soluble monomer isopropylacrylamide polymerization can be initiated, so as to achieve the purpose of reactive black KN-B dye polymerization. The mode can make the functionalization and the polymerization reaction not interfere with each other, the degree of freedom of operation is large, there are many types of products, the polymerization reaction conditions are mild, and organic solvents and emulsifiers are not used, which meets the requirements of green chemistry.

The invention relates to a method for polymerizing a naphthalimide fluorescent dye. Synthesize a kind of amphiphilic compound containing 4-amino-1,8-naphthalimide fluorescent group and tertiary amine structure, can be used as the initiator of free radical polymerization, and its tertiary amine can react with potassium persulfate at normal temperature Oxidation-reduction reactions occur, and active free radicals are generated many times, which can initiate the polymerization of oil-soluble monomer styrene and water-soluble monomer acrylamide on the water / oil interface, so as to realize the polymer of naphthalimide fluorescent dye For the purpose of chemicalization, this mode can make functionalization and polymerization do not interfere with each other, has a large degree of freedom of operation, a variety of products, mild polymerization conditions, no organic solvents and emulsifiers, and meets the requirements of green chemistry.

The invention relates to a polymerization method of fluorescein dye. Synthesize an amphiphilic compound containing a fluorescein group and a tertiary amine structure, which can be used as an initiator for free radical polymerization, and its tertiary amine can undergo redox reactions with potassium persulfate at room temperature to generate active free radicals many times , on the water / oil interface, both the oil-soluble monomer acrylonitrile polymerization and the water-soluble monomer acrylic acid polymerization can be initiated, so as to achieve the purpose of polymerizing the fluorescein dye. This mode can make the functionalization and the polymerization reaction interact No interference, large degree of freedom of operation, many types of products, mild polymerization reaction conditions, no organic solvents and emulsifiers, which meet the requirements of green chemistry.

The invention relates to a method for preparing vinylidene fluoride / N, N-dimethylacrylamide copolymers in a green manner. The vinylidene fluoride / N, N-dimethylacrylamide copolymers are used as separation membrane materials. The method has the advantages that the method is a copolymer synthesis technology based on water / oil two-phase interfacial free radical polymerization, oxidation-reduction reaction is carried out by special Gemini surface active initiators and potassium persulfate at the normal temperature, free radicals are repeatedly generated on interfaces, independent polymerization reaction between vinylidene fluoride and N, N-dimethylacrylamide is initiated, two types of chain segments are connected with each other by initiator molecules in series to form the segmented copolymers, the feed ratios of monomers are extremely consistent with component ratios of the copolymers when pH (potential of hydrogen) values of water-phase media are within the ranges of 4.0-4.5 as proved by experiments, the content of N, N-dimethylacrylamide chain segments in the copolymers is adjustable in the ranges of 5-25 wt.%, polymerization reaction conditions in the modes are mild and controllable, the method is low in energy consumption, other organic solvents or emulsifiers can be omitted, products are pure, and requirements on green chemistry can be completely met.

The invention relates to a green preparation method of a vinyl chloride / isoprene copolymer as a thermoplastic elastomer. The preparation method is copolymer synthetic technology formed based on water / oil interfacial free radical polymerization. The preparation method is characterized by specially using a gemini surface active initiator to carry out redox reaction with potassium persulfate under normal temperature, repeatedly generating free radicals on the interfaces for multiple times and triggering independent polymerization reaction between vinyl chloride and isoprene and connecting the two chain segments together in series by initiator molecules, thus forming the multiblock polymer. Experiments prove that when the pH value of the aqueous medium is 4-4.5, the feed ratio of monomers is quite consistent with the component ratio of the copolymer; the content of the isoprene chain segment in the copolymer is adjustable in the range of 10-42wt.%; the polymerization reaction in such a mode is mild and controllable in conditions, is low in energy consumption and dispenses with other organic solvents and emulsifiers; the product is pure and completely meets the requirements of green chemistry.

The invention relates to a gemini type hydrazide anion initiator and its preparation and use method. Synthesize an amphiphilic compound containing a disulfonate group and a hydrazide group, which has the characteristics of a surfactant. At the same time, the hydrophilic hydrazide can undergo redox reactions with potassium persulfate at room temperature, and can repeatedly generate free radicals , flexibly control the multi-phase serial polymerization, initiate the polymerization of styrene and vinyl acetate and styrene and acrylamide in sequence on the water / oil interface, and obtain multi-block copolymers. The composition ratio of the compounds is very consistent, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, low energy consumption, no other organic solvents and emulsifiers, and the product is pure, which fully meets the requirements of green chemistry.

The present invention relates to a polymerization method for dispersing scarlet dye S-BWFL. Synthesize an amphiphilic compound containing dispersed red azo group and tertiary amine structure, which can be used as an initiator of free radical polymerization. Free radicals can initiate the polymerization of the oil-soluble monomer vinyl chloride and the water-soluble monomer β-hydroxyethyl acrylate on the water / oil interface, thereby achieving the purpose of polymerizing the disperse scarlet dye S-BWFL. This mode can make functionalization and polymerization do not interfere with each other, has a large degree of freedom of operation, a variety of products, mild polymerization conditions, no organic solvents and emulsifiers, and meets the requirements of green chemistry.

The invention relates to a sodium isooctylhydrazide sulfonate initiator and its preparation and use method. Synthesize a compound containing bis-sulfonate anion and isooctylhydrazide group, which has the characteristics of surfactant. At the same time, hydrazide can undergo redox reaction with potassium persulfate at room temperature, and can repeatedly generate free radicals, which can be flexibly controlled Multi-phase serial polymerization, styrene and methyl methacrylate and styrene and hydroxyethyl acrylate are sequentially initiated on the water / oil interface to obtain multi-block copolymers. The composition ratio is very consistent, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, the energy consumption is low, and other organic solvents and emulsifiers are not used. The product is pure and fully meets the requirements of green chemistry.

The invention relates to an amphiphilic acetylhydrazine initiator and its preparation and use method. Synthesize a compound containing octadecyl chain and hydrazide, which has the characteristics of surfactants. At the same time, hydrazide can undergo redox reaction with potassium persulfate at room temperature, which can repeatedly generate free radicals and flexibly control multi-phase series. Direct polymerization, styrene and methyl methacrylate and styrene and hydroxyethyl acrylate are sequentially initiated on the water / oil interface to obtain multi-block copolymers. Experiments have proved that the ratio of monomer feed to copolymer composition It is very consistent, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, the energy consumption is low, no other organic solvents and emulsifiers are used, and the product is pure, which fully meets the requirements of green chemistry.

The invention relates to a bisphosphonate interface initiator and a preparation method thereof. Synthesize a tertiary amine compound containing bisphosphonate anion and didodecanyl to make it exhibit a stronger emulsification function than ordinary surfactants, and at the same time, the tertiary amine can undergo redox reaction with potassium persulfate at room temperature, Cationic free radicals are first formed on nitrogen atoms, and then converted into carbon free radicals at adjacent positions. The generation of free radicals can be repeated many times, flexibly controlled, and multi-phase series polymerization is realized, which is initiated sequentially on the water / oil interface. Styrene and methyl methacrylate and styrene and hydroxyethyl acrylate to obtain multi-block copolymers. Experiments have proved that the feed ratio of monomers is very consistent with the composition ratio of copolymers, indicating that the initiator has a higher initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, the energy consumption is low, no other organic solvents and emulsifiers are used, and the product is pure, which fully meets the requirements of green chemistry.

The invention relates to a Gemini type hydrazide anion initiator and preparation and use methods thereof. An amphiphilic compound containing a bissulfonate radical and a hydrazide group is synthesized, and has the characteristics of a surfactant, and the hydrophilic hydrazide can undergo redox reaction with potassium persulfate at normal temperature, and free radicals can be repeatedly generated.Multi-phase tandem polymerization is flexibly controlled, and polymerization of styrene and vinyl acetate and polymerization of styrene and acrylamide are initiated in sequence at a water / oil interface to obtain a multi-block copolymer. Experiments prove that the monomer feed ratio is consistent with the composition ratio of the copolymer, and it is indicated that the initiator has high initiationefficiency. The polymerization conditions of the mode are mild and controllable, energy consumption is low, no other organic solvents and emulsifiers are adopted, the product is pure, and the requirements of green chemistry are fully met.

The present invention relates to a polyhydroxy tribasic hydrazide initiator and a preparation and use method thereof. Synthesis of an amphiphilic compound containing three hydrazide groups, the compound has the characteristics of positioning at the water / oil two-phase interface, and the hydrazide in the hydrophilic part can undergo redox reaction with potassium persulfate at room temperature, The free radicals can be repeatedly generated for many times, so as to flexibly control the multiphase tandem polymerization mode, and sequentially initiate the polymerization of styrene and vinyl acetate and styrene and N-vinylpyrrolidone at the water / oil interface to obtain multi-block Copolymer, the experiment proves that the ratio of the monomer to the material is very consistent with the composition ratio of the copolymer, indicating that the initiator has a high initiation efficiency. The polymerization reaction conditions of this mode are mild and controllable, low energy consumption, and no other organic solvents and emulsifiers are needed. , the product is pure and fully meets the requirements of green chemistry.