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Carbon-coated pre-magnesium silicon monoxide negative electrode material and preparation method thereof

PendingCN122091513AHigh porosityImprove ionic conductivityMagnesium silicatesCell electrodesCarbon coatingPorous layer
The invention discloses a carbon-coated pre-magnesium silicon monoxide negative electrode material and a preparation method thereof, the negative electrode material comprises a silicon core, a silicon-magnesium composite porous layer and a carbon-coated layer, the silicon-magnesium composite porous layer comprises MgSiO3 and Mg2SiO4 with porous characteristics, and the porosity is not less than 30%; the material shows a unique peak position and intensity relationship in an XRD diffraction pattern, and Mg2SiO4 is used as a main phase. According to the preparation method, through molten salt mediated low-temperature solid-phase reaction and addition of reducing gas during heat treatment, energy consumption is greatly reduced, a generated Mg2SiO4 crystal structure is more stable than traditional MgSiO3, and a porous structure (porosity is larger than 30%) formed through the cooperation reaction enables the material to maintain high capacity of 1621.49 mAh / g, meanwhile, the first efficiency is improved to 85.91%, and the cyclic expansion rate is reduced by 40% or above.
Owner:CNBM ZHEJIANG MATERIAL TECH CO LTD