The invention discloses a composition for increasing the sunscreen value of a sunscreen emulsion and a preparation method of the composition. Water, octyl polymethylsiloxane, ethylhexyl triazinone, diethylaminohydroxybenzoyl hexyl benzoate, diethylhexyloxyphenol methoxyphenyl triazine, ethylhexyl methoxycinnamate, octocrilene, Tween 60 or tribehenin PEG-20 ester or polyglycerol-3 diisostearate andglyceryl stearate citrate combined components are adopted. A prepared emulsion preform in a sub-micro stable state is transferred into an ultrasonic cell disruptor for treatment, a treated water phase preform phase is added, homogenizing and uniform stirring are carried out to obtain a target product. According to the emulsion prepared by the method, the usage amount of an emulsifier and a sunscreen agent can be reduced, the cost is saved, and the influence of large usage amount of the raw materials on skin, such as irritation, is reduced; The prepared emulsion is smaller in liquid drop and more uniform in sunscreen component distribution, the sunscreen value of the sunscreen emulsion is increased, the skin feeling is fresher, and meanwhile, the stability is better.