The invention discloses a lead storage battery positive electrode plate taking 4BS-graphene as an additive and a preparation method of the positive electrode plate. The positive electrode plate comprises the raw materials of lead powder, 4BS, graphene, acetylene black and red lead; and the positive electrode plate has the main components of <beta>-PbO<2>, <alpha>-PbO<2> and graphene. According tothe lead storage battery positive electrode plate taking 4BS-graphene as the additive and the preparation method of the positive electrode plate, a seed crystal effect is played in positive electrodecuring by virtue of addition of 4BS, the size and uniform distribution degree of 4BS in the unprocessed positive electrode plate can be optimized, the relative contents and structures of the <alpha>-PbO<2> and <beta>-PbO<2> in the finished electrode plate can be adjusted, and beneficial influences to the performance, particularly prolonging of the service life, of the positive electrode of the lead acid battery can be realized; by adding graphene to the electrode material, the conductive performance of the electrode can be improved effectively, the deep layer active materials with the electrode micropore structure can be fully utilized, the discharge capacity is increased, and negative effects of relatively high content of <alpha>-PbO<2> in the positive electrode finished electrode plate to the positive electrode capacity caused by taking 4BS as the additive can be counteracted.