The utility model relates to the technical field of heat pumps, and discloses a non-azeotropic mixed working medium
heat pump system which comprises a compressor and a
refrigerant circulation loop which is connected with the compressor and forms a loop with the compressor, and a condenser, a first throttling device, a
liquid storage device and an
evaporator are sequentially arranged on the
refrigerant circulation loop in the
refrigerant flow direction. The
liquid storage device is provided with a refrigerant inlet, a first refrigerant outlet and a second refrigerant outlet, the refrigerant inlet is connected with the first throttling device, the first refrigerant outlet is connected with an inlet of the
evaporator, the second refrigerant outlet is connected with the inlet of the
evaporator through a bypass pipeline, and an
electric control valve is arranged on the bypass pipeline. According to the
heat pump system, low-boiling-point components in gaseous working media account for a large amount, namely, refrigerant components actually participating in the whole
defrosting circulation account for a large amount, so that
high pressure in the
defrosting circulation is improved,
mass flow is increased, finally, acting of a compressor is larger, namely, condensation heat dissipating capacity of
defrosting of an evaporator is larger, and
energy consumption is reduced. Therefore, the defrosting effect of the non-azeotropic mixed working medium
heat pump system is improved.