The invention provides a compound cladding positive pole material of a
lithium ion battery and a preparation method of the compound cladding positive pole material. The positive pole material comprises a positive pole material base body and a cladding layer, wherein the cladding layer comprises two parts: a
metal oxide main body framework layer with a porous three-dimensional structure, a
surface layer distributed on the main body framework layer and a rapid
ion conductor layer located in a pore. The compound cladding layer produced by the method has a relatively large and controllable specific surface area, and the contact between the cladding layer and
electrolyte can be effectively improved, and the rate performance of the material can be effectively improved; meanwhile, the compound cladding layer has good
chemical stability, and a contact
side reaction between the positive pole material base body and the
electrolyte is inhibited; and meanwhile, the damages to the surface cladding layer of the material, caused by the deformation in a rolling process of a
pole piece, and the tension change of the cladding layer in a circulating process are inhibited; and the degradation of the positive pole material in the circulating process can be effectively improved and the circulating stability of the battery is improved.