The invention relates to an airport road surface ice accretion early warning system and an early warning method thereof. The system is composed of a data acquisition and monitoring center and a data center; the data acquisition and monitoring center includes a wind speed sensor, an ambient temperature sensor, a road surface temperature and humidity sensor, a temperature sensor, a signal conditioning board, a protocol conversion module, a first wireless communication module, a router, a man-machine interaction interface, an icing early warning device and a monitoring terminal; and the data center includes a second wireless communication module, an Internet network, an airport base station server and a mobile terminal. The airport road surface ice accretion early warning system and the early warning method thereof of the invention have wireless data transmission, mobile terminal on-site monitoring and ice accretion early warning functions. According to the airport road surface ice accretion early warning system and the early warning method thereof of the invention, probabilistic prediction for field road surface ice accretion conditions can be realized through using temperature and ice accretion models and according to the local temperature, road surface relative humidity, wind speed and road surface and internal temperature of an airport, and therefore, early warning signals can be accurately emitted to ground dispatchers and ground supporting personnel, and preparations for de-icing operation can be made.