The invention discloses a dynamic 
thermal infrared invisible 
composite material based on dual 
phase change and a preparation method and especially relates to a VO2 / 
mica based 
phase change heat-accumulation 
thin layer composite material and a preparation method, and belongs to the technical field of preparation of 
infrared invisible materials. The VO2 / 
mica based 
phase change heat-accumulation thinlayer 
composite material is composed of a VO2 
nanoparticle coating and a 
mica based phase change heat-accumulation 
thin layer, wherein the mica based phase change heat-accumulation 
thin layer is composed of 
stearic acid and a 
vanadium-extracted mica matrix according to the 
mass ratio of (3 to 5) to (5 to 7). The preparation method comprises the following step: preparing VO2 nanoparticles from 
vanadium-extracted mica by adopting a 
roasting and acid leaching technology; taking the 
vanadium-extracted mica as a supporting matrix and embedding to a phase change functional body to prepare the mica based phase change heat-accumulation thin layer; and 
coating the mica based phase change heat-accumulation thin layer with the VO2 nanoparticles to obtain a dual phase change composite material. The dynamic 
thermal infrared invisible composite material based on the dual phase change, provided by the invention, can be used for cooperatively strengthening the 
thermal infrared invisible performance and can be applied to a thermal 
infrared invisible technology.