106results about "Coupling reaction in azo dyes" patented technology

A method of producing a fine particle of an organic pigment, containing the steps of: flowing a solution of an organic pigment dissolved in an alkaline or acidic aqueous medium, through a channel which provides a laminar flow; and changing a pH of the solution in the course of the laminar flow.

There is provided a colorant compound improved in the dispersibility of an azo pigment into a water-insoluble solvent. The colorant compound is represented by the following general formula (1). R1 denotes an alkyl group having 1 to 6 carbon atoms, or a phenyl group; R2 to R6 each denote a hydrogen atom, or a substituent represented by the following general formula (2); R7 to R11 each denote a hydrogen atom, a COOR12 group, or a CONR13R14 group; and R12 to R14 each denote a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms; and P1 denotes a polymeric component; L1 denotes an alkylene group having 1 to 3 carbon atoms or an arylene group having 6 to 10 carbon atoms; and * denotes a binding site.

The present invention relates to a novel polymeric composition comprising a novel polymer having two or more repeat units and a terminus having the structure (1):wherein R1 represents a C1-C20 substituted or unsubstituted alkyl group, w is a number from 1-8, X is oxygen (O) or nitrogen (N), and Rd is a reactive group. The invention also relates to a process for forming a pattern using the novel polymeric composition. The invention further relates to a process of making the novel polymer.

Black disazo dyes of general formula (V)whereinA is a moiety of formula (VI)or of formula (VII)andB is a moiety of formula (VIII)or of formula (IX)and wherein M, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23 and R24 are as defined in the specification, are excellent black dyes for dying and printing cellulose containing materials and textile materials and, in particular, for the preparation of recording liquids for ink jet printing and for writing utensils.

A polarizing film or polarizing plate containing, as a dichroic dye, an azo compound whose free acid form is represented by the following formula (1): wherein R1 and R2 each independently represents sulfo, carboxy, lower alkyl, or lower alkoxy; R3 represents lower alkyl, lower alkoxy, or acetylamino; R4 to R6 each independently represents hydrogen, lower alkyl, lower alkoxy, or acetylamino; and R7 represents hydrogen, amino, or hydroxy. The polarizing film and plate are excellent in polarizing performance and durability and are highly reduced in color leakage in the visible light region.

The present invention describes methods for preparing aqueous colored pigment dispersions comprising the step of combining, in any order, a) a colored pigment, b) an azo coupler, c) an aromatic amine, d) a diazotizing agent, and e) an aqueous medium, wherein the aromatic amine comprises as least one ionic group, at least one ionizable group, or a mixture of at least one ionic group and at least one ionizable group. These colored pigment dispersions are particularly useful as an inkjet ink composition. Also disclosed are inkjet ink compositions comprising a) a liquid vehicle, b) a colored pigment, and c) a dispersant having the formula:D-N═N-AC,wherein AC is an azo coupling component and D is a diazo component comprising at least one ionic group, at least one ionizable group, or a mixture of at least one ionic group or ionizable group.

A polarizing film or polarizing plate containing, as a dichroic dye, an azo compound whose free acid form is represented by the following formula (1):wherein R1 and R2 each independently represents sulfo, carboxy, lower alkyl, or lower alkoxy; R3 represents lower alkyl, lower alkoxy, or acetylamino; R4 to R6 each independently represents hydrogen, lower alkyl, lower alkoxy, or acetylamino; and R7 represents hydrogen, amino, or hydroxy. The polarizing film and plate are excellent in polarizing performance and durability and are highly reduced in color leakage in the visible light region.

A liquid crystalline coating solution which comprises: an azo compound represented by the following general formula (I); and a solvent to dissolve the azo compound:wherein Q1 is a phenyl group or a naphthyl group (these groups may have any substituent groups); Q2 is a pheylene group or a naphtylene group (these groups may have any substituent groups); m is an integer from 1 to 5; and M is a counter ion.

The invention is directed to an electrophotographic toner or developer, powder coating, ink jet ink or an electronic media having an azo colorant prepared by conducting the diazotization of aromatic or hetaromatic amines or the azo coupling reaction or the diazotization and the azo coupling reaction in a microreactor.

Naphthol AS pigments of formula (IV) have a maximum content of the secondary components (1) to (5) defined by the following upper limits (see the table).

A mixing apparatus including a plurality of nozzle groups each formed of nozzles for ejecting the same fluid arranged in group, the nozzles being provided with openings for ejecting fluid, to cause the plurality of nozzle groups to separately eject a plurality of fluids to mix the fluids in areas on the extending lines of the nozzles, wherein the openings of the nozzles forming the nozzle groups are arranged along annular loci and the plurality of nozzle groups are arranged coaxially to each other, a plurality of supplying channels for supplying the plurality of fluids to the nozzle groups corresponding to the plurality of nozzle groups are annular in cross section in the direction perpendicular to the direction in which fluid supplied to the supplying channels flows and arranged coaxially to each other.

To provide an azo pigment composition having extremely good hue and extremely good light fastness and showing excellent tinctorial strength (color density) and, preferably, to provide an azo pigment composition further containing an azo pigment having characteristic X-ray diffraction peaks at different positions or a tautomer thereof An azo pigment composition which contains at least one azo pigment represented by the following formula (1) and having characteristic peaks at Bragg angles (20±0.2°) of 7.2° and 25.9° in X-ray diffraction with the characteristic Cu Kα line, or a tautomer thereof:.

To provide an azo pigment composition exhibiting very good hue and light fastness and having excellent tinctorial strength (color density) and preferably further provide an azo pigment composition containing an azo pigment having characteristic X-ray diffraction peaks at different positions or a tautomer thereof. An azo pigment composition comprising at least one kind of an azo pigment represented by formula (1) having characteristic X-ray diffraction peaks at Bragg angles(20±0.2°) of 7.6°, 25.6° and 27.7° in the CuKα characteristic X-ray diffraction or a tautomer thereof:

A method of coupling a diazonium salt with an organic polymer comprising, on order, the steps of: providing a polymer in one liquid phase; providing a diazonium salt in a separate liquid phase; contacting the separate phases, and thereby reacting the polymer and the diazonium salt.

The invention relates to the field of dye preparation, particularly a grinding coupling method for preparing a disperse dye. According to the grinding coupling method for preparing a disperse dye, a coupling component and a diazonium salt are subjected to coupling reaction in the presence of a grinding medium to obtain the disperse dye. The method provided by the invention obviously reduces the discharge of acidic wastewater, enhances the unit volume yield, lowers the consumption of the cold source, saves the subsequent commercial grinding time due to the pre-ground crude dye, and synthesizes the dye on the basis of the insoluble coupling component, thereby providing a practical method capable of saving the material consumption and energy consumption and obtaining a high-quality dye filter cake without coupling component residues. The obtained crude dye is equivalently subjected to pre-dispersion grinding treatment, and about 10-20% of milling time can be saved when the crude dye is sent to the subsequent procedure for commercial processing. The energy-saving coupling of the disperse dye is implemented through the control on optimized technological conditions.

The present invention relates to a magenta ink for inkjet recording containing at least one pigment selected from the group consisting of C.I. Pigment Red 147, 150, 176, 266 and 269, in an amount of 0.5 to 10% by mass relative to the total mass of the ink. The present invention can provide a magenta ink that is comprehensively superior in terms of light resistance, color development and storage stability. The present invention can also provide an ink set having excellent light resistance and color development for each ink included in the ink set, and an inkjet recording method that uses the ink set.

The invention discloses a preparation technique for azo disperse dyes, which comprises preparing esterification solution and coupling reacting. Wherein, the esterification solution comprises mainly one of: 1) 3-N, N-acetoxylated amido-4-methoxyl-1-acetanilide; 2) N- cyanoethyl-N-acetoxylated amido aniline; 3) 3-N, N-acetoxylated amido-1-acetanilide. This invention increases concentration of esterification solution from 65% to about 90% to decrease COD in waste water more than 60%, and has high efficiency.

The invention is directed to an electrophotographic toner or developer, powder coating, ink jet ink or an electronic media having an azo colorant prepared by conducting the diazotization of aromatic or hetaromatic amines or the azo coupling reaction or the diazotization and the azo coupling reaction in a microreactor.

The invention is directed to an electrophotographic toner or developer, powder coating, ink jet ink or an electronic media having an azo colorant prepared by conducting the diazotization of aromatic or hetaromatic amines or the azo coupling reaction or the diazotization and the azo coupling reaction in a microreactor.

Disclosed herein are a reaction method and a production method of an organic compound which are capable of achieving high reaction selectivity according to the purpose and a high production rate of a target substance. The methods include at least two fluids, wherein at least one kind of the fluids is a fluid containing at least one organic compound and at least one kind of the fluids other than the above fluid is a fluid containing at least one reactant in the form of a liquid or solution, and the respective fluids join together in a thin film fluid foamed between processing surfaces arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, whereby an organic reaction is performed in the thin film fluid.

There is provided an azo pigment having excellently good color reproducibility, dispersibility, and storage stability of pigment dispersions and having excellent hue and tinctorial strength. An azo pigment represented by the following formula (1) and having characteristic peaks at Bragg angles (20±0.2°) of 7.2°, 13.4°, 15.0° and 25.9° in X-ray diffraction with characteristic Cu Kα line, and a tautomer thereof:

A monoazo lake pigment composition containing a monoazo lake pigment obtained from a laked pigment aqueous slurry prepared by conducting coupling of a diazo component obtained by diazotizing an aromatic amine having a soluble group and a coupler component and conducting laking after or simultaneously with the coupling, wherein the laking is carried out in the presence of a water-soluble acrylic polymer in an amount of 0.1 to 40 parts by weight per 100 parts of the above coupler component, and a gravure ink containing the above pigment composition and a gravure ink vehicle.

A liquid crystalline coating solution which comprises: an azo compound represented by the following general formula (I); and a solvent to dissolve the azo compound:wherein Q1 is a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group; Q2 is a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group; m is an integer from 1 to 5; and M is a counter ion.

Disclosed is an azo compound represented by the general formula (1) or a salt thereof:wherein R1 and R2 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxy group; and n represents 1 or 2. Also disclosed are a dye-containing polarizing film and a dye-containing polarizing plate, each of which comprises a polarizing film base material and the azo compound contained in the base material.

The lyotropic liquid crystalline mixture of the present invention comprises at least a first azo compound and a second azo compound in relation of constitutional isomers wherein the first azo compound and the second azo compound are the constitutional isomers different in a binding site of at least an azo group. The first azo compound is preferably an azo compound wherein the azo group is bonded to an ortho-position of a hydroxyl group of an aminonaphthol skeleton. The second azo compound is preferably an azo compound wherein the azo group is bonded to an ortho-position of an amino group of an aminonaphthol skeleton.The lyotropic liquid crystalline mixture of the present invention may be utilized as a forming material of an optical anisotropic film, for example.

To provide an azo pigment composition having extremely good hue and extremely good light fastness and showing excellent tinctorial strength (color density) and, preferably, to provide an azo pigment composition further containing an azo pigment having characteristic X-ray diffraction peaks at different positions or a tautomer thereof.An azo pigment composition which contains at least one azo pigment represented by the following formula (1) and having characteristic peaks at Bragg angles (2θ±0.2°) of 7.2° and 25.9° in X-ray diffraction with the characteristic Cu Kα line, or a tautomer thereof:

The present invention is to provide a charge controlling agent and negatively chargeable toner that do not contain any toxic metal, are essentially free from the risk of evoking ignition or explosion, and can exhibit a high charge amount and rapid initial increase in charging.The charge controlling agent is a mono azo iron complex compound represented by Formula (1):wherein J represents H, alkali metal, ammonium, or alkyl ammonium, or two or more of those elements in combination.

The present invention provides Pigment Yellow 180 having an excellent transparency produced by using a fine slurry of 5-acetoacetylamino-benzimidazolone as a coupling component when Pigment Yellow 180 is produced by coupling reaction of 5-acetoacetylamino-benzimidazolone and diazo component obtained by diazotization of 1,2-bis(2-aminophenoxy)ethane.

The present invention is to provide a charge controlling agent and negatively chargeable toner that do not contain any toxic metal, are essentially free from the risk of evoking ignition or explosion, and can exhibit a high charge amount and rapid initial increase in charging. The charge controlling agent is a mono azo iron complex compound represented by Formula (1): wherein J represents H, alkali metal, ammonium, or alkyl ammonium, or two or more of those elements in combination.