The application discloses a kind of mesoporous
silicon carbon composite materials with multistage structure and preparation method and application, belong to
silicon carbon negative
electrode material synthesis technical field.The preparation method of the mesoporous
silicon carbon composite materials with multistage structure includes the following steps: after mixing silicon
powder and
persulfate solution, oxidation treatment is carried out, then the obtained product is dispersed in
oleic acid and
surface modified, to obtain silicon@
oleic acid dispersion liquid;
Carbon source,
citric acid, surfactant and initiator are pre-assembled in water, then the silicon@
oleic acid dispersion liquid is added to carry out
polymerization reaction, to obtain silicon@oleic acid@
polymer precursor;Under
inert atmosphere, the silicon@oleic acid@
polymer precursor is carbonized, to obtain the mesoporous silicon carbon
composite material with multistage structure.The material as
lithium ion battery negative material can significantly improve the rate performance and cycle stability of
lithium ion battery.