The application discloses a preparation method of a ZIF / LDH loaded
biochar composite adsorbent and application thereof, and comprises the following steps: (1) mixing, calcining and washing and
drying pretreated corn stalks and alkali to obtain
biochar BC; (2) mixing, washing,
drying and calcining a certain proportion of the
biochar BC and acetate, then mixing with 2-methyl
imidazole, aging, and washing and
drying to obtain BC / ZIF; and (3) immersing a certain amount of BC / ZIF in a
nitrate solution, stirring, standing, washing and drying to obtain a BC / ZIF8 / LDH composite adsorbent. The composite adsorbent has a layered and
open structure, a large specific surface area, a large number of adsorption sites, and a
nitrosamine precursor removal rate of more than 95%; has a good binding capacity and
selective adsorption on small-molecule amine,
histidine,
protein and other
nitrogen disinfection by-product N-DBPs precursors; has good dispersing performance, high
utilization rate of LDH
metal, stable structure, good reaction activity and good repeated use effect; and has a wide source of raw materials, low price, low production cost and high economic benefit.