The invention relates to a deep ultraviolet laser photoluminescent spectrometer, which comprises a full solid deep ultraviolet laser, a vacuum sample chamber, a vacuum monochrometer, a first vacuum maintaining system, a second vacuum maintaining system, a low-temperature system, a temperature control device, a sample frame three-dimensional adjusting device, a stable state emission spectrum detection system, a time resolution spectrum detection system, a vacuum leakage safety system and a computer control device, wherein the vacuum sample chamber is connected with the full solid deep ultraviolet laser; the vacuum monochrometer is connected with the vacuum sample chamber; the first vacuum maintaining system is connected with the vacuum sample chamber; the second vacuum maintaining system is connected with the vacuum monochrometer; the low-temperature system and the temperature control device and the vacuum sample chamber are connected by a flange; the sample frame three-dimensional adjusting device is connected with the vacuum sample chamber; the stable state emission spectrum detection system is connected with the vacuum monochrometer; the time resolution spectrum detection system is connected with the vacuum monochrometer; the first control end and the second control end of the vacuum leakage safety system are connected with the first vacuum maintaining system, the third control end and the fourth control end of the vacuum leakage safety system is connected with the second vacuum maintaining system, and the fifth control end of the vacuum leakage safety system is connected with the low-temperature system and the temperature control device; and the computer control device is used for controlling the vacuum leakage safety system, the vacuum monochrometer, the low-temperature system, the temperature control device, the sample frame three-dimensional adjusting device, the stable state emission spectrum detection system and the time resolution spectrum detection system.