The invention discloses a preparation method of a PAN-based
solid-
solid phase change material, which comprises the following steps: step 1, uniformly mixing
acrylonitrile and
phase change monomers, and heating until all the monomers are completely molten to form a uniform
liquid system; adding an emulsifier, a
chain transfer agent and deionized water into the
liquid system, and completely emulsifying all monomers to obtain a stable
emulsion system; step 2, placing the
emulsion system in an
oxygen-free environment, and adding an initiator solution for free
radical polymerization reaction to obtain a polymerized
emulsion system; step 3, adding the polymerized emulsion system into the
salting-out agent solution, and standing to form a
polymer precipitate; and washing the
polymer precipitate to remove unreacted monomers and impurities, and
drying to remove
moisture, thereby obtaining the PAN-based
solid-solid
phase change material. According to the invention, PAN is taken as a main chain, a
side chain with a phase change function is introduced through free radical copolymerization, and a brand-new
polymer type phase change
energy storage material is constructed.